This invention relates to a method for producing chromates, especially for producing
alkali metal chromates. The method comprises following steps: the obtaining of a mixture of
alkali metal hydroxide,
alkali metal chromate, and
ferrous residue after the reaction of
chromite ore with an oxidant in the reactor in the presence of
molten salt or in
aqueous solution of alkali
metal hydroxide, the obtaining of a leaching
slurry by leaching the reaction products with
aqueous solution of alkali
metal hydroxide, the separating of the primary chromate product from the leaching
slurry, the obtaining of pure chromate
crystal by purifying the primary chromate product. Both the primary chromate product and the pure chromate
crystal can be used as the raw materials to manufacture other
chromium compounds. Compared with the currently-used
roasting method, the method has the advantages of decreasing the
reaction temperature by about 700° C., of improving the
chromium recovery rate up to nearly 100%, of minimizing the amount of the
ferrous residue by not adding
calcium-containing auxiliaries, and of completely eliminating the disposal problem of the
chromium-containing residue and the environmental
pollution due to the addition of
calcium-containing auxiliaries, by using
ferrous residue as the raw materials for other industries after extraction of
magnesium.