The invention relates to a nanometer composite
metal oxide with doped MoO3-SnO2 base and preparing method thereof; the chemical
general equation of the nanometer composite
metal oxide with doped MoO3-SnO2 base can be expressed as: Y-MoO3-SnO2, wherein, the
mole ratio of Sn / Mo is 0.1 to 10 : 1, Y represents the doped
metal oxide, and the quality ratio of the metal elements of the Y and the Sn is 0 to 0.05 :1; the invention adopts a
fractional precipitation method, comprising the following steps: Alpha-stannic acid precipitate is prepared by pink salt, the filtered precipitate is scattered in the water so as to prepare Alpha-stannic acid
sol the concentration of which is 0.02 to 0.2M,
molybdenum salt solution is added by dipping, the pH value is regulated till the
precipitation is completed, and the nanometer composite
powder is prepared by
drying and
roasting; the
powder is prepared into a sensor element which has higher sensitivity for NO2, CO and C2H5OH, the sensitivity and the selectivity thereof for NO2, CO and C2H5OH gas are improved by
doping and wrapping a little of metal oxide, thus reducing the
cross sensitivity of the NO2, CO and C2H5OH gas.