The invention relates to a technology for detecting chlorobenzene compounds and particularly relates to a method for determining the chlorobenzene compounds in a plastic product. The method comprises the following steps: (1) sample preparation: selecting samples and crushing the samples into uniform samples with a high polymer material sample crusher; (2) extraction: adding the samples into a solvent, tightly plugging, extracting in a microwave extractor, filtering extract liquor, blowing with nitrogen and waiting for purification; (3) purification: activating a PA (polyamide) pillared with a solvent, adding the samples into the solvent for dissolution, eluting with the solvent, blowing to be dry with nitrogen and metering volume with propyl alcohol; (4) gaschromatographic mass spectrometric determination: respectively absorbing a to-be-determined standard solution and a to-be-determined sample solution, injecting a gaschromatographic mass spectrometer for determining and finally calculating the content of chlorobenzene compounds in the samples. The determination method provided by the invention has the advantages that 12 types of chlorobenzene organic compounds in plastics can be simultaneously detected, therefore, the sensitivity is relatively high, the limit of detection is low, the degree of precision is good, the detection period is short, the anti-interference capacity is strong, and the method is fast, stable and accurate.