The invention discloses a spherodial graphite cast iron cast gear and a machining process thereof. The spherodial graphite cast iron cast gear mainly comprises, by weight, 3.5%-3.6% of C, 2.3%-2.4% of Si, 0.4%-0.45% of Mn, less than 0.1% of Cr, 0.4%-0.45% of Cu, 0.03%-0.045% of Mg, not larger than 0.02% of S, not larger than 0.05% of P and the balance Fe. The machining process of the gear includes the following steps of firstly, molten iron smelting, secondly, spheroidizing inoculation, thirdly, casting molding, fourthly, shot blasting, fifthly, thermal treatment, sixthly, rough machining, seventhly, surface hardening and eighthly, finish machining. According to the cast gear, low-manganese scrap steel serves as a raw material, production cost can be lowered, and the gear cast through spherodial graphite cast iron has the comprehensive performances of being high in strength, high in wear resistance and high in flexibility and can meet the requirement of a transmission gear.