The invention relates to the field of solar cells, and discloses a
solar cell, a preparation method thereof and a photovoltaic module. The
solar cell comprises a
cell substrate, wherein at least one side surface of the
cell substrate is provided with a groove structure; the
electrode structure is arranged at the groove structure, the
electrode structure comprises a conductive
metal layer, the conductive
metal layer comprises a first sub-part and a second sub-part which are connected, the groove structure is filled with the first sub-part, and the second sub-part is exposed out of the battery substrate; the surface of the second subpart is coated with the anti-oxidation layer, the
oxidation resistance of the anti-oxidation layer is higher than that of the conductive
metal layer, and the anti-oxidation layer is configured to be prepared by placing the battery substrate containing the conductive metal layer in a reaction solution containing anti-oxidation metal ions; along the thickness direction of the
cell substrate, the H1 of the first sub-part and the H2 of the second sub-part satisfy the following conditions: 1 < = H1 < 3 [mu] m, and 5 < = H2 < = 15 [mu] m. The
electrode structure on the
solar cell is high in stability and good in current collection effect.