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47 results about "Dichloroethene" patented technology

Dichloroethene or Dichloroethylene, often abbreviated as DCE, can refer to any one of several isomeric forms of the organochloride with the molecular formula C₂H₂Cl₂: There are three isomers: 1,1-Dichloroethene 1,2-Dichloroethene

Azeotropic or azeotrope-like compositions for solvent and single-phase or two-phase cleaning applications

The invention discloses a series of azeotropic or azeotrope-like compositions for solvent and single-phase or two-phase cleaning applications, and the formula of the azeotropic or azeotrope-like compositions mainly comprises trans-1, 2-dichloroethylene and hexafluoropropylene dimer; the composition may include at most one of 1, 1, 2, 2-tetrafluoroethyl-2, 2, 2-trifluoroethyl ether or 1, 1, 2, 3, 3, 3-hexafluoropropyl-2, 2, 2-trifluoroethyl ether, for example, 60 to 80% by mass of trans-1, 2-dichloroethylene, 20 to 40% by mass of hexafluoropropylene dimer or 60 to 65% by mass of trans-1, 2-dichloroethylene, or may also include any at most one of 1, 1, 2, 2-tetrafluoroethyl-2, 2, 2-trifluoroethyl ether or 1, 1, 2, 3, 3, 3-hexafluoropropyl-2, 2, 2-trifluoroethyl ether, for example, 60 to 80% by mass of trans-1, 2-dichloroethylene, 20 to 40% by mass of hexafluoropropylene dimer or 60 to 65% by mass of 1, 1, 2, 2- 25 to 30% by mass of a hexafluoropropylene dimer; and 10 to 15% by mass of any one of HFE347 or HFE449. According to the present invention, the component capable of generating the azeotrope-like composition with the trans-1, 2-dichloroethylene component can inhibit the flash point of the trans-1, 2-dichloroethylene component so as to improve the safety performance of transportation, storage and use. The multi-component composition described by the formula can be used for high-efficiency degreasing of metal parts or high-efficiency cleaning of precise devices in the metal processing process, can also be used as a solvent, a degreasing agent, a desoldering agent or a drying agent and the like, and can meet multiple application requirements.
Owner:SHANGHAI FLUORO IND CO LTD

Synthesis method of 3-oxo-1-cyclobutyl carboxylic acid

The invention discloses a novel method for synthesizing 3-oxo-1-cyclobutanecarboxylic acid, which comprises the following steps: taking dichloroacetyl chloride or trichloroacetyl chloride as a starting raw material, carrying out elimination reaction in a solvent under the catalytic action of alkali or Zn-Cu, and reacting the obtained dichloroketene intermediate with methyl acrylate in situ to generate 3-oxo-2, 2, 3-trimethyl-1-cyclobutanecarboxylic acid, thereby obtaining the 3-oxo-1-cyclobutanecarboxylic acid. The 3-oxo-1-cyclobutanecarboxylic acid is prepared by using 2, 2-dichloro-1-cyclobutanecarboxylic acid as a raw material, then dehalogenation and hydrolysis reactions are carried out to prepare the 3-oxo-1-cyclobutanecarboxylic acid, the 3-oxo-1-cyclobutanecarboxylic acid is a pure product with the content of 99% or above, and the total yield reaches 50% or above. The synthetic route has the advantages of mild conditions, few byproducts, high yield and environmental friendliness, and is suitable for industrial amplification.
Owner:DALIAN RES & DESIGN INST OF CHEM IND

High-barrier polypropylene material, preparation method thereof and application of high-barrier polypropylene material in organic silica gel sealing packaging material

The invention discloses a high-barrier polypropylene material, a preparation method thereof and application of the high-barrier polypropylene material in an organic silica gel sealing packaging material, and relates to the technical field of high polymer materials. When the high-barrier polypropylene material is prepared, firstly, polypropylene is grafted with dichloro (vinyl) phosphine and vinylmethylsilane and then reacts with 1-ethylene-1H-pyrrole to obtain modified polypropylene, secondly, pretreated montmorillonite is subjected to demethylation through aluminum chloride and then reacts with 2-chloro-5-(1H-pyrrole-1-yl) pyridine to obtain the high-barrier polypropylene material. Then carrying out a reaction with N-triethyl-(4-vinylbenzyl) ammonium to obtain modified montmorillonite; and finally, mixing the modified polypropylene and the modified montmorillonite to obtain the high-barrier polypropylene material. The high-barrier polypropylene material prepared by the invention has high barrier rate, flame retardant property and ultraviolet aging resistance.
Owner:SHANTOU JINGTONG IND

Dichloroethylene rectifying tower

The utility model discloses a dichloroethylene rectifying tower which comprises a tower body, one side of the tower body is fixedly connected with a liquid inlet pipe, the lower end of the tower body is fixedly connected with a liquid discharge pipe, one side of the liquid inlet pipe is fixedly connected with a connecting pipe, and one side of the connecting pipe is fixedly connected with a shunting ring pipe. A plurality of nozzles are fixedly connected to the lower end of the shunting ring pipe, a first honeycomb plate, a second honeycomb plate and a third honeycomb plate are arranged in the tower body, and a first guide plate, a second guide plate and a third guide plate are arranged in the tower body; by arranging the first honeycomb plate, the second honeycomb plate, the third honeycomb plate, the first guide plate, the second guide plate and the third guide plate, a gas phase rises through the lower part of the tower body, a liquid passes through the first honeycomb plate, the second honeycomb plate and the third honeycomb plate, and under the guide action of the first guide plate, the second guide plate and the third guide plate, the contact time of the gas phase and the liquid is long; therefore, the liquid and the gas phase can be more fully mixed.
Owner:NINGXIA PURUI CHEM CO LTD

Azeotropic or azeotrope-like compositions containing (Z)-1-chloro-2,3,3-trifluoroprop-1-ene (HCFO-1233yd(Z)) and solvent uses thereof

Azeotropic or azeotrope-like compositions, particularly azeotropic or azeotrope-like compositions consisting essentially of or consisting of (Z)-1-chloro-2,3,3-trifluoroprop-1-ene (HCFO-1233yd(Z)), ethanol, and each of methanol, as well as azeotropic or azeotrope-like compositions consisting essentially of or consisting of (Z)-1-chloro-2,3,3-trifluoroprop-1-ene (HCFO-1233yd(Z)), ethanol, and 1,2-trans-dichloroethylene (trans-DCE), and azeotropic or azeotrope-like compositions consisting essentially of or consisting of (Z)-1-chloro-2,3,3-trifluoroprop-1-ene (HCFO-1233yd(Z)), methanol, and 1,2-trans-dichloroethylene (trans-DCE), and solvent uses of the aforementioned compositions.
Owner:HONEYWELL INTERNATIONAL INC

Low-VOC precise instrument cleaning agent and cleaning method

The invention provides a low-VOC (volatile organic compound) precise instrument cleaning agent. The low-VOC precise instrument cleaning agent is prepared from trans-dichloroethylene, isopropanol, a fluorocarbon solvent, a dicarbonyl compound and organic amine, the content of the trans-dichloroethylene is not less than 50% by mass, the content of the isopropanol is not less than 1% by mass, the content of the fluorocarbon solvent is not less than 30% by mass, the content of the dicarbonyl compound is not less than 2% by mass, and the content of the organic amine is not less than 1% by mass; wherein the fluorocarbon solvent is one or more of methyl (ethyl) nonafluorobutyl ether, methyl (ethyl) nonafluoroisobutyl ether, 3-methoxy-2-trifluoromethyl octafluorobutane, perfluorotriethylamine, perfluorotripropylamine, perfluorotributylamine, a perfluoropropylene oligomer (dimer or trimer) and perfluorohexanone. The precise cleaning agent prepared through the scheme has good cleaning capacity for scaling powder and metal salt, scaling powder residues on the inner surface and the outer surface of a complex circuit are effectively removed, and an important guarantee is provided for stable production of electronic products.
Owner:ZHONGKEWEI NEW MATERIALS (SHENZHEN) CO LTD

Azeotropic and azeotrope-like compositions comprising 1,2-dichloroethylene and 1h,2h-octafluorocyclopentane and use of the compositions as flash spinning agents

The present invention relates to (i) an azeotropic or azeotrope-like composition comprising (a) cis-1,2-dichloroethylene and cis-1H,2H-octafluorocyclopentane or comprising (b) trans-1,2-dichloroethylene and trans-1H,2H-octafluorocyclopentane, (ii) a spin fluid for flash spinning comprising these azeotropic or azeotrope-like compositions and a polyolefin, and (iii) a process for the preparation of plexifilamentary fibrils of polyolefin using the spin fluid.
Owner:DUPONT SAFETY & CONSTRUCTION INC

Preparation method of solvent-corrosion-resistant and high-heat-sealing-strength coating film for packaging

The invention discloses a preparation method of a solvent-corrosion-resistant and high-heat-sealing-strength packaging coating film. The preparation method comprises the following steps: S1, preparing a modified polyvinylidene chloride emulsion; the modified polyvinylidene chloride emulsion is prepared by mixing the following raw materials in parts by weight: 80-89 parts of copolymerized vinylidene chloride emulsion with the medium polymerization degree solid content of 40%-50%, 10 parts of distilled water and 1-10 parts of accelerant, and reacting at preset temperature and pressure; s2, preparing an inorganic nano silicon dioxide solution, wherein the inorganic nano silicon dioxide solution is prepared by mixing 1-10 parts by weight of inorganic nano silicon dioxide, 87-98.9 parts by weight of distilled water and 0.1-3 parts by weight of an emulsifier. The preparation method of the solvent-corrosion-resistant high-heat-sealing-strength packaging coating film provided by the invention overcomes the defects that the coating of the coating film is corroded and damaged by a solvent or an aromatic, the peeling strength of the coating of the coating film is low, the coating film is adhered in the processing process, and an additive is separated out.
Owner:ZHEJIANG YIBAI PACKAGING MATERIALS CO LTD

Aqueous latex of vinylidene chloride copolymer

An aqueous latex [latex (L)] of a vinylidene chloride copolymer [copolymer (A)], wherein the copolymer (A) consists essentially ofrecurring units derived from vinylidene chloride (VDC) in an amount comprised between 89.0 and 91.0 wt % of the copolymer,recurring units derived from methacrylonitrile (MAN) in an amount comprised between 2.00 and 5.50 wt % of the copolymer,recurring units derived from at least one ionic comonomer (ICO) in an amount comprised between 0.5 and 1.4 wt % of the copolymer (A), andrecurring units derived from methylmethacrylate (MMA) in an amount such that the total of recurring units of VDC, MAN, ICO and MMA is 100 wt %,and wherein the latex (L) comprises at least one surfactant [surfactant (S)] in an amount comprised between 0.09 and 1.50 wt % of the copolymer (A).Process for the manufacture of the aqueous latex (L), film made therefrom and retort pouch prepared with such film.
Owner:SYENSQO SA

Continuous preparation process of p-chloro-o-cresol

The invention relates to the technical field of organic synthesis, and discloses a continuous preparation process of p-chloro-o-cresol, which comprises the following steps: mixing o-cresol and dichloroethylene, reacting with sulfuryl chloride in the presence of a proper catalyst, and controlling the reaction process by adopting staged sulfuryl chloride addition rate to avoid the occurrence of polychlorination side reaction. The reaction temperature is kept between 5 DEG C and 15 DEG C, products are effectively separated and recycled through a rectification and tail gas treatment system, and generation of by-products is reduced. The process has the advantages of mild reaction conditions, lower catalyst dosage, higher product purity and better environmental protection effect, is suitable for large-scale industrial production, and has higher resource utilization efficiency.
Owner:HUAIAN WANGZHOU IMPORT & EXPORT CO LTD

Azeotropic composition, azeotrope-like composition, composition, cleaning agent, solvent, heat transfer medium

The present invention provides an azeotropic composition, a quasi-azeotropic composition, and a composition that have little impact on the global environment, are non-flammable, and are not prone to composition changes even after repeated evaporation and condensation, as well as a cleaning agent, a solvent, and a heat transfer medium containing the azeotropic composition, the quasi-azeotropic composition, or the composition. An azeotropic composition, which is composed of 34.5% by mass of (Z)-1-chloro-2,3,3-trifluoropropene and 65.5% by mass of trans-1,2-dichloroethylene; an azeotropic composition, which is composed of 28 to 41% by mass of (Z)-1-chloro-2,3,3-trifluoropropene and 59 to 72% by mass of trans-1,2-dichloroethylene.
Owner:AGC INC

Method for preparing trans-1, 2-dichloroethylene through electro-catalysis

The invention provides a method for preparing trans-1, 2-dichloroethylene through electro-catalysis. The method is a novel process for preparing the trans-1, 2-dichloroethylene by using clean and renewable electric energy as driving force and a chlorine-containing aqueous solution as a chlorine source and by constructing an electro-catalytic reaction system at normal temperature and normal pressure, and can meet the requirements on an environment-friendly trans-1, 2-dichloroethylene preparation process at the present stage; the method has the advantages of high selectivity, high reaction efficiency and low energy consumption.
Owner:NORTHWESTERN POLYTECHNICAL UNIV +1

High-barrier composite film

InactiveCN120535804APolymer scienceMeth-
The invention discloses a high-barrier composite film, and relates to the technical field of film materials. Comprising the following raw materials: 20 to 30 parts of a functional copolymer, 40 to 60 parts of an ethylene-vinyl alcohol copolymer, 5 to 8 parts of cellulose nanocrystals, 2 to 4 parts of a compatilizer, 0.5 to 1 part of an antioxidant, 0.8 to 1.2 parts of a lubricant, 3 to 5 parts of 1-allyl-3-vinyl imidazole chlorine salt and 1 to 2 parts of allyl-beta-cyclodextrin. The functional copolymer comprises a structural unit introduced by the following monomers: vinylidene chloride, 2-acrylamido-2-methylpropanesulfonic acid, 3-(1, 1-difluoro-2-propylene-1-yl)-2 (1H)-quinoxalinone, and N-(4-cyano-3-trifluoromethylphenyl) methacrylamide. The film is good in mechanical property, good in barrier property, excellent in damp-heat aging resistance and long in service life.
Owner:JIANGSU QIANRUN NEW MATERIAL TECH CO LTD

Azeotrope-like solvent blends exhibiting low global warming potential and methods of use

Cleaning solvent blends comprising an HCFO such as l-chloro-2,3,3,- trifluoropropene; trans-dichloroethylene; and a high boiling HEE such as HFE-7300; have utility as a non-flammable, low-global warming potential, azeotrope-like cleaning solvent compositions. Additional solvent ingredients may include surfactants and co-solvents. A method for cleaning articles of soiling substances comprises contacting the articles with the solvent composition by any suitable means such as a spray delivered by a propellant gas, or by contact with liquid and / or vapor solvent compositions, as in a conventional vapor degreaser apparatus, and removing the composition from the articles.
Owner:ZYNON TECHNOLOGIES LLC

Azeotropic or azeotropic-like composition comprising hydrogen fluoride and 1,1,2-trichloroethane, trans- 1,2-dichloroethylene or cis-1,2-dichloroethylene

An object of the present invention is to provide a novel azeoropic or azeotrope-like composition that is effective for the separation of HF from 1,1,2-trichloroethane (HCC-140), trans-1,2-dichloroethylene (HCO-1130(E)), or cis-1,2-dichloroethylene (HCO-1130(Z)). The object can be achieved by an azeotropic or azeotrope-like composition comprising HCC-140, HCO-1130(E), or HCO-1130(Z), and hydrogen fluoride.
Owner:DAIKIN INDUSTRIES LTD

Solvent compositions and associated methods

A nonflammable solvent composition comprises, based on the total weight of trans-1,2-dichloroethylene, (E)-1-chloro-2,3,3-trifluoroprop-1-ene, and (Z)-1-chloro-2,3,3-trifluoroprop-1-ene: about 80 wt. % to about 99.99 wt. % of trans-1,2-dichloroethylene; and about 0.01 wt. % to about 20 wt. % of at least one of (E)-1-chloro-2,3,3-trifluoroprop-1-ene or (Z)-1-chloro-2,3,3-trifluoroprop-1-ene; wherein the nonflammable solvent composition has no fire point over a temperature range of 10° C. to the boiling point of the solvent composition, measured according to any one or more of ASTM D92-18, ASTM D1310-14, or ASTM D56-22. Methods for preparing a nonflammable solvent composition from trans-1,2-dichloroethylene and for increasing the fire point of trans-1,2-dichloroethylene comprises mixing the trans-1,2-dichloroethylene with about 0.01 wt. % to about 20 wt. % of at least one of (E)-1-chloro-2,3,3-trifluoroprop-1-ene or (Z)-1-chloro-2,3,3-trifluoroprop-1-ene to form a nonflammable solvent composition having no fire point over a temperature range of 10° C. to the boiling point of the solvent composition.
Owner:SHELLEF HLDG

Azeotropic and azeotrope-like compositions comprising a chlorinated compound and a c6-hydrocarbon and use of the compositions as flash spinning agents

The present invention relates to (i) an azeotropic or azeotrope-like composition comprising (1) a chlorinated compound selected from the group consisting of trichloromethane, cis-1,2-dichloroethylene, and trans-1,2-dichloroethylene, and (2) a linear or branched C6 hydrocarbon, selected from the group consisting of n-hexane, 2-methylpentane, 3-methylpentane, 2,2-dimethylbutane, and 2,3-dimethylbutane, (ii) a spin fluid for flash spinning comprising these azeotropic or azeotrope-like compositions and a polymer, and (iii) a process for the preparation of plexifilamentary fibrils of polymers using the spin fluid.
Owner:DUPONT SAFETY & CONSTRUCTION INC

Treatment system for calcium chloride raffinate generated in vinylidene chloride production process

The utility model discloses a system for treating calcium chloride raffinate generated in the production process of vinylidene chloride, which comprises a collecting and adjusting tank, an inlet end of which is used for introducing and collecting the raffinate after saponification reaction is finished; the inlet end of the neutralizing tank is connected with the outlet end of the collecting and adjusting tank; the inlet end of the coagulation tank is connected with the outlet end of the neutralizing tank; the inlet end of the post-coagulation wastewater temporary storage tank is connected with the liquid outlet of the coagulation tank; the inlet end of the sand filter is connected with the outlet end of the coagulated wastewater temporary storage tank, and the inlet end of the activated carbon filter is connected with the outlet end of the sand filter; the inlet end of the ultrafiltration device is connected with the outlet end of the activated carbon filter, and the outlet end of the ultrafiltration device is connected with the ultrafiltration wastewater temporary storage tank; the inlet end of the reverse osmosis device is connected with the outlet end of the ultra-filtered wastewater temporary storage tank; and the evaporating crystallizer is connected with a concentrated solution outlet of the reverse osmosis device and is used for evaporating and crystallizing.
Owner:JINCHUAN GROUP CO LTD +1

An ionic liquid containing boron-containing oxygen ring and benzene ring, a preparation method and application thereof

The application discloses an ionic liquid containing a boron-containing oxygen ring and a benzene ring, a preparation method and application, and the ionic liquid is obtained by the reaction of tris(trimethylsilyl) borate, dichloroethylene, 4-p-chlorophenyl imidazoline and diisopropylamine; the ionic liquid can be used for alcoholysis of PET to obtain DMT, improve the conversion rate of DMT, and has a significant prospect in the application of PET degradation and recycling of DMT.
Owner:WUHAN HISPRING TECH DEV CO LTD

Pressure SIS control system for synthesizing trans-dichloroethylene

The invention relates to the technical field of chemical process control, and discloses a pressure SIS control system for trans-dichloroethylene synthesis, which comprises a synthesis monitoring module, a multi-source data acquisition module, a parameter adjustment module, an early warning module, a human-computer interaction interface module and a self-adaptive optimization module, the multi-source data acquisition module acquires data, the data analysis module calculates a synthesis pressure supplement coefficient, a synthesis temperature supplement coefficient and a pressure early warning value of the jth workshop section, the parameter adjustment module adjusts the pressure and temperature of the synthesis reaction according to the calculation result, and the early warning module performs real-time grading early warning according to the numerical range of the pressure early warning value. The man-machine interaction interface module displays the system operation state, key parameters and early warning information and receives an instruction of an operator to realize man-machine interaction, and the self-adaptive optimization module optimizes the system performance according to historical data and real-time monitoring data.
Owner:NINGXIA PURUI CHEM CO LTD

Preparation method of catalytic cracking reaction composite metal catalyst and application of catalytic cracking reaction composite metal catalyst in preparation of vinylidene chloride

The invention belongs to the technical field of catalysts, and particularly relates to a preparation method of a catalytic cracking reaction composite metal catalyst and application of the catalytic cracking reaction composite metal catalyst in preparation of vinylidene chloride, and the preparation method of the catalytic cracking reaction composite metal catalyst comprises the following steps: (1) mixing a chitosan solution and an acetic acid solution, adjusting the pH value to obtain a mixed solution, adding the zinc lactate solution into the mixed solution, and uniformly mixing to obtain a zinc chelate solution; (2) mixing the zinc chelate solution, an aluminum-containing compound, a silicon-containing compound and a template agent to form slurry, performing spray granulation to form molecular sieve particles, and performing crystallization, washing and drying to obtain zinc-containing molecular sieve microspheres; (3) mixing cesium sulfate, oleic acid and octadecene for reaction to obtain a cesium oleate solution; and (4) dispersing the zinc-containing molecular sieve microspheres into a cesium oleate solution for reaction to obtain the composite metal catalyst for catalytic cracking reaction. According to the preparation process, the process conditions are optimized, and a perfect catalytic system is formed.
Owner:SHANDONG XINGLU CHEM CO LTD

Solvent compositions and associated methods

A nonflammable solvent composition comprises a nonflammable solvent and optionally, an additive composition. The nonflammable solvent comprises: about 90.0 wt. % to about 99.99 wt. % of trans-1,2-dichloroethylene; and about 0.01 wt. % to less than about 10.0 wt. % of one or more of (E)-1-chloro-2,3,3-trifluoroprop-1-ene and (Z)-1-chloro-2,3,3-trifluoroprop-1-ene, based on the total weight of trans-1,2-dichloroethylene, (E)-1-chloro-2,3,3-trifluoroprop-1-ene, and (Z)-1-chloro-2,3,3-trifluoroprop-1-ene. The nonflammable solvent composition has no fire point as determined by flammability testing compliant with any one or more of ASTM D92 or ASTM D1310.
Owner:SHELLEF HLDG

Preparation method of catalytic cracking reaction composite metal catalyst and application thereof in preparation of vinylidene chloride

The present application belongs to the technical field of catalysts, and particularly relates to a preparation method of a catalytic cracking reaction composite metal catalyst and application thereof in preparation of vinylidene chloride, the preparation method of the catalytic cracking reaction composite metal catalyst comprising the following steps: (1) mixing a chitosan solution with an acetic acid solution, adjusting pH to obtain a mixed solution, and then adding a zinc lactate solution into the mixed solution and mixing uniformly to obtain a zinc chelate solution; (2) mixing the zinc chelate solution, an aluminum-containing compound, a silicon-containing compound and a template agent to form a slurry, forming molecular sieve particles through spray granulation, crystallizing, washing and drying to obtain zinc-containing molecular sieve microspheres; (3) mixing cesium sulfate, oleic acid and octadecene to obtain a cesium oleate solution through a mixing reaction; and (4) dispersing the zinc-containing molecular sieve microspheres into the cesium oleate solution to react, and obtaining the catalytic cracking reaction composite metal catalyst. The present application optimizes process conditions in the preparation process, and forms a perfect catalytic system.
Owner:SHANDONG XINGLU CHEM CO LTD

Slurry washing and impurity removing process and device and application of slurry washing and impurity removing process and device

The invention discloses a washing and impurity-removing process and device for desorbed slurry in a vinylidene chloride polymerization production process and application of the washing and impurity-removing process and device. The slurry washing and impurity-removing process comprises the following steps: transferring desorbed slurry into a washing kettle with an overflow port, spraying cold water to the top of the washing kettle, introducing hot water into the bottom of the washing kettle, swelling resin in the slurry to remove impurities by alternately carrying out cold and hot impact washing, and overflowing the impurities out of the washing kettle along with water through the overflow port under stirring, part of the resin flows out from the bottom of the washing kettle along with water and is circularly pumped back below the liquid level of the slurry washing mixed liquid in the washing kettle through the washing circulating pump. The slurry washing and impurity removing device comprises a washing kettle with an overflow port, a cold water spraying device is arranged at the top in the washing kettle, the bottom in the washing kettle is connected with a hot water inlet pipe and a discharging pipe, the discharging pipe is connected with one end of a washing circulating pump, and the other end of the washing circulating pump is connected with the washing kettle through a return pipe. And the outlet of the material return pipe is positioned below the liquid level of slurry washing mixed liquid in the washing kettle.
Owner:ZHEJIANG ENG DESIGN +2

High-toughness antibacterial PVDC composite film and preparation method thereof

The invention relates to the technical field of films, and discloses a high-toughness antibacterial PVDC composite film and a preparation method thereof.The high-toughness antibacterial PVDC composite film is prepared from, by weight, 100 parts of 1, 1-dichloroethylene, 10-15 parts of methyl acrylate, 10-15 parts of 2-ethylhexyl acrylate, 5-10 parts of a modified mesoporous silica-based cardanol product, 1-3 parts of an emulsifier and 2-5 parts of an initiator. According to the present invention, the main raw materials are all from biomass, such that the raw materials have characteristics of no toxicity and green, and can be used in the field of packaging films, and the prepared composite film has excellent antibacterial property and excellent mechanical property.
Owner:ANHUI TIANJIA NEW MATERIAL TECH CO LTD

Azeotrope or azeotrope-like compositions comprising (Z)-1-chloro-2, 3, 3-trifluoroprop-1-ene (HCFO-1233yd (Z)) and solvent applications thereof

An azeotrope or azeotrope-like composition, in particular an azeotrope or azeotrope-like composition consisting essentially of (Z)-1-chloro-2, 3, 3-trifluoroprop-1-ene (HCFO-1233yd (Z)) with or consisting of each of ethanol and methanol, and an azeotrope or azeotrope-like composition consisting essentially of (Z)-1-chloro-2, 3, 3-trifluoroprop-1-ene (HCFO-1233yd (Z)) with or consisting of each of ethanol and methanol. The present invention relates to an azeotrope or azeotrope-like composition consisting of or consisting of (Z)-1-chloro-2, 3, 3-trifluoroprop-1-ene (HCFO-1233yd (Z)), ethanol and trans-dichloroethylene (trans-DCE), and an azeotrope or azeotrope-like composition consisting of or consisting of substantially (Z)-1-chloro-2, 3, 3-trifluoroprop-1-ene (HCFO-1233yd (Z)), methanol and trans-dichloroethylene (trans-DCE), and to a method for producing the same. The invention also discloses solvent application of the composition.
Owner:SOZOTEX PERFORMANCE MATERIALS AMERICA INC

Vapour phase catalytic process for the selective conversion of HCC-140 to HCFC-142

The invention provides a process for manufacturing 1-chloro-2,2-difluoroethane (HCFC- 142) from 1,1,2-trichloroethane (HCC-140) and optionally, one or more of E / Z-1,2- dichloroethene (HCO-1130(E / Z)), E / Z-1-fluoro-2-chloroethene (HCFO-1131(E / Z)), and 1- fluoro-1,2-dichloroethane (HCFC-141). The invention also provides to a process for manufacturing a difluoroethyl derivative from HCFC-142 obtained using the process of the invention.
Owner:MEXICHEM UK LIMITED

Membrane condensation recovery device for 1, 1-dichloroethylene organic waste gas

The utility model belongs to the technical field of waste gas treatment, and particularly relates to a membrane-method condensation recovery device for 1, 1-dichloroethylene organic waste gas. Comprising a vinyl chloride waste gas raw material pipeline, the vinyl chloride waste gas raw material pipeline is connected with a demister through a deacidification tower, the demister is connected with a buffer tank, the buffer tank is connected with a gas-liquid separation tank through a compressor, the gas-liquid separation tank is connected with a condenser through a precooler, the condenser is connected with a liquid collection tank, and the liquid collection tank is connected with the precooler through a non-condensable gas pipeline. The precooler is connected with the membrane separation system, the upstream of a membrane of the membrane separation system is connected with the oxygen cracking system, the downstream of the membrane of the membrane separation system is connected with the buffer tank, the gas-liquid separation tank is provided with a working liquid circulation pipeline, a compressor outlet pipeline is provided with a machine head outlet temperature transmitter, and the working liquid circulation pipeline is provided with a pH meter. The waste gas is firstly subjected to deacidification and demisting treatment, and the temperature of the waste gas at the outlet of the compressor is monitored, so that the risk of agglomeration of waste gas components in the device is reduced, and the liquid level in the gas-liquid separator is automatically controlled within a certain range.
Owner:SHANDONG XINGLU CHEM CO LTD