The invention relates to a normal temperature
methane high-efficiency adsorption material and a preparation method thereof. The material is characterized in that a
metal organic skeleton
composite material containing transition metals Fe III, Zn II, Cu II, Ni II and Co III grows on an
active carbon ceramic mainly prepared from
active carbon and
molecular sieve in an in situ manner. The preparation method of the normal temperature
methane high-efficiency adsorption material comprises the following steps: carrying out
dry mixing and ball milling on one or more of chlorides and sulfates of Fe<3+>, Zn<2+>, Cu<2+>, Ni<2+> and Co<3+>, high-specific surface area coconut shell
active carbon, Y
molecular sieve, attapulgite, kaolin and
methyl cellulose in proportion, adding a certain amount of water, carrying out wet mixing, kneading, carrying out vacuum pugging,
ageing, carrying out
extrusion molding,
drying in the shade, carrying out
microwave irradiation sizing to obtain an active carbon
ceramic molding material containing transition metals, immersing the molding material in a
mixed solution containing an
organic solvent, an deprotonated alkali and an organic
carboxylic acid ligand according to a certain ratio, reacting at 120-180DEG C for 6-24h, carrying out
solid-liquid separation, washing, and carrying out
microwave vacuum drying to obtain a
metal organic skeleton-active carbon
ceramic composite material. The material has the characteristics of large specific surface area, developed aperture, high
compressive strength, large
methane adsorption capacity and high CH4 / N2 and CH4 / CO2 separation coefficients, and can be widely used in the fields of
methane pressure swing
adsorption separation and low-concentration methane
recovery.