The application discloses a photochemical
ionization time-of-flight
mass spectrometry VOCs atmospheric on-line monitoring device and method, which comprises a complete
ion generation and analysis
system formed by a plurality of
gas mixing cavities, photochemical
ionization cavities, differential vacuum cavities,
radio frequency quadrupole cavities,
electrostatic lens cavities and TOF detection zones in series, and is equipped with an automatic gas path
control system; the application integrates an intelligent closed-
loop control system; the
system uses a three-dimensional
ion detection system to acquire time and space quality parameters of an
ion beam in real time, combines with a current hardware state of the instrument, and calculates 12-dimensional hardware parameter adjustment instructions in real time through a
convolutional neural network model; the application solves the performance drift problem of a traditional
mass spectrometer caused by environmental changes through the construction of an intelligent
closed loop of sensing-diagnosis-decision-execution, realizes the autonomous optimization, long-term stable and high-precision operation of the instrument, and significantly improves the
automation level, accuracy and reliability of atmospheric VOCs on-line monitoring.