The invention discloses an online
measurement device and measurement method for the NO concentration in a high-NO2 and low-NO
atmosphere. The online
measurement device comprises an
ozone generation unit, a connection
pipe cleaning unit and a sampling
pipe, wherein a connection reaction bin, an NO2
measuring instrument, a second
mass flow meter and a first
air pump are sequentially connected behind the sampling
pipe; and the connection pipe cleaning unit comprises an electromagnetic three-way valve, an
activated carbon tube, a current-limiting hole and a second
air pump. By adopting a cavity-
enhanced absorption spectroscopy, a sampling mode (actual
atmosphere of
ozone is added) or a zero point mode (actual
atmosphere) is set through the electromagnetic three-way valve; absorption spectrum intensity signals of two
modes are measured through an NO2
measuring instrument as a sampling spectrum and a reference spectrum respectively, and then NO in the atmosphere is converted into a concentration value of the NO2 through
spectral fitting, that is to say, measurement of the NO concentration in the atmosphere environment is achieved, so that the online
measurement device and measurement method have the characteristics of being free of NO2 concentration interference, a low
detection limit, high sensitivity, high temporal-spatial resolution, high stability and low cost.