The present invention provides a single set of
mass spectrometer capable of selectively performing the following two
modes of analyses according to the purpose of analysis: the first
mass spectrometry mode in which the analysis can be repeated at short intervals of time; and the second
mass spectrometry mode in which the analysis can be performed with high mass resolution and high accuracy. In an embodiment of the present invention, ions ejected from an
ion source 1 travel along a
straight path B, on which gate electrodes 3 are provided. When a
voltage is applied from an MS
mode selection controller 7 to the gate electrodes 3, the ions are introduced into a loop
orbit A. Located on the loop
orbit A is a second
ion detector 6, which is a nondestructive type of
ion detector. Detection signals of the second ion
detector 6 are sent to a data processor 9, which extracts
flight time spectrum data from those signals and Fourier-transforms those data to convert the time axis to a
frequency axis. From the
frequency spectrum thus created, the mass-to-charge ratio of each ion is calculated with high accuracy. When no
voltage is applied to the gate electrodes 3, the ions ejected from the
ion source 1 travel along the
straight path B and arrive at a first ion detector 5. This mode of analysis requires only a short period of time and can achieve a high level of
time resolution.