The invention provides Baijiu prepared by collectively brewing green tea seeds and cereals. Baijiu is prepared by adopting the raw materials as follows: green tea seeds and red sorghums. The method comprises the following steps: shelling green tea seeds, and pulverizing the green tea seeds into powder; boiling the green tea seed powder with clean water in a pot into paste; cooling the green tea seed paste, adding active dry yeast, mixing, stacking, sealing with screen cloth, covering with vinasse for 12 hours for standby use; washing and rinsing red sorghums, discharging slag, and immersing the red sorghums in clean water for 12 hours; draining, steaming in a bamboo container, and obtaining a viscose material with no hard core for standby use; uniformly mixing the viscose material and distiller yeast, stacking, sealing with the screen cloth, covering with the previous vinasse, placing into a fermenting pool, sealing with a plastic film, and fermenting for 30 days; additionally taking dry spring tealeaves which are 4 percent of the total weight of the green tea seeds and the red sorghums, and immersing in 90-DEG-C hot water before being loaded into the bamboo container for standby use; and placing the fermented material into a wine container, spraying once when each layer of tealeaves is laid, and steaming Bajiu according to a traditional distilling way. The cereal Baijiu produced by virtue of the method is excellent in quality, fragrant in flavor and strong, has the tea fragrance, is mellow in taste and long-lasting in aftertaste.