The invention discloses a method of comprehensive exploitation and utilization on atmospheric carbon resources and CO2 equivalent substance, which is a comprehensive science and technology method by applying physics, chemistry, physical chemistry, biology, biochemistry and the like. Substance such as CO, CO2, hydrocarbons, oxygenated hydrocarbons, hydrofluorocarbon, perfluorocarbon, sulfur hexafluoride and NOx in the atmosphere is captured, sealed, comprehensively developed, deeply processed and recycled, thereby benefiting the mankind, regulating the greenhouse effects, eliminating the haze, mastering the initiative of climate changes, maintaining water-air-ice coexistence climate balance and biodiversity on the earth, creating huge environmental benefits, ecological benefits, social benefits and economic benefits, realizing win-win between economic and social development, environmental protection and climate change handling, and providing inexhaustible new resources and precious wealth for human survival and development.