The invention relates to an industrial wastewater physicochemical treatment agent and an application thereof. A physicochemical treatment material HB-F001, a physicochemical treatment oxidizing and adsorbing agent HB-F002 and a physicochemical treatment solid-liquid separating agent HB-F003 are applied to industrial wastewater treatment through stirring, adsorbing, reacting, separating, circulating and the like. The industrial wastewater physicochemical treatment agent solves the problems that the iron-carbon bed hardening subsequent treatment efficiency is low, electricity consumption is high, more materials are consumed and more solid wastes are generated during electrolysis, secondary pollution is caused by plenty of salt generated by repeatedly adjusting the Fenton treatment pH value, the application ranges of photocatalysis and ultrasonic waves are limited, ozone is high in electricity consumption and high in investment, ozone is generated unstably and the treatment effects are unstable, and solves the problems of high treatment cost of a wet oxidation process and safety. The industrial wastewater physicochemical treatment agent substantially increases the wastewater pollutant control and pollution factor removal rate, satisfies reuse water biochemical treatment conditions and treatment cost, is sustainable and stable, avoids secondary pollution, is low in cost, has quite high application values, and really achieves the effect of environmental protection.