The invention relates to the field of solar cells, in particular to a
solar cell piece and a preparation method thereof, a laminated
cell and a photovoltaic module, and the prepared
solar cell piece comprises a
silicon substrate, and an aluminum
oxide interface modification layer, a tunneling
oxide layer, a heavily doped
polycrystalline silicon layer, a back
passivation film layer and a back
electrode which are sequentially arranged from the back of the
silicon substrate from inside to outside, the front emitting
electrode, the front passive film layer and the front
electrode are sequentially arranged on the front face of the
silicon substrate from inside to outside, and the thickness of the aluminum
oxide interface modification layer is smaller than that of the tunneling oxide layer. According to the
cell, the aluminum oxide interface modification layer is inserted between the back surface of the silicon
wafer and the tunneling oxide layer, fixed negative charges and high
dielectric constant of aluminum oxide are utilized, interface positive charges are neutralized, the interface
state density is reduced, meanwhile, it is ensured that the
electron tunneling efficiency is not affected, and the problem of insufficient
passivation caused by Si-SiOX interface defects of an existing
cell silicon
wafer is solved; and finally, the conversion efficiency and the long-term stability of the battery and the manufactured photovoltaic module are improved.