The invention discloses an application of an anti-
corrosion commercial
coating as a
zinc negative
electrode coating in an Ah-grade
zinc metal soft
package battery by introducing an additive into the anti-
corrosion commercial
coating, and belongs to the technical field of aqueous
zinc metal secondary batteries. The invention uses
tallow amines as additives to be introduced into commercial coatings. Under the action of an
electric field, the preferentially adsorbed
tallow amine is chemically adsorbed with zinc, so that the acting force between the coating and the zinc negative
electrode is enhanced, and the coating is prevented from falling off. Meanwhile, water-related side reactions are effectively inhibited through coating modification, ordered deposition of zinc ions is guided, an
electric field is uniform, the effect of inhibiting dendritic
crystal growth is achieved, and the electrochemical reversibility of the zinc negative
electrode is improved. Therefore, the ZnZn symmetric battery assembled by using the zinc negative electrode containing the
tallow amine coating circulates for 1500 hours at the
current density of 2 mA cm <-2 >; the assembled ZnMnO2 button type total battery circulates for 500 circles under the
current density of 1A g <-1 >; the soft
package battery circulates for 15 circles under the
current density of 2 mA cm <-2 >, and has the capacity of 1.0 Ah. The preparation process is simple, the effect is remarkable, the cost is low, and the requirements of environmental
economic benefits are met.