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92 results about "T2 relaxation" patented technology

Core stress sensitivity measuring method

The invention discloses a core stress sensitivity measuring method based on nuclear magnetic resonance. Core stress sensitivity is measured on the basis of conventional displacement experiments and nuclear magnetic resonance testing methods. The method includes the steps that core pretreatment is conducted; a core is subjected to pressurized saturation to simulate formation water; the core is placed in a non-magnetic core clamp to be fixed to an NMR coil; confining pressure is set to test the nuclear magnetic resonance T2 relaxation spectrum of the core; stress values are set for repeated testing at intervals; the highest static stress values are sequentially reduced from 20 MPa to 2.5 MPa, each stress value is kept for a certain period of time to test the T2 spectrum, and the current conventional permeability and NMR permeability are obtained through computation; a core conventional stress sensitivity curve is drawn. By means of the method, people can understand the core stress sensitivity change rule from the micro perspective, characteristics such as pore size distribution, porosity changes and NMR permeability in the experiment process are provided, and change rules of microfracture compact matrix limestone pore size distribution, porosity and permeability in stress sensitivity testing can be effectively detected.
Owner:PEKING UNIV

Methods of decoupling diffusion effects from relaxation times to determine properties of porous media containing fluids

Novel pulse sequences are used to probe the properties of porous media, such as are found in subterranean formations and core samples. This use allows diffusion effects to be uncoupled from the overall T2 relaxation time of the sample. Properties such as internal field gradient and distribution of diffusion coefficients may be determined. A series of pulse sequences are applied to the media to be evaluated. The series of pulse sequences include first and second windows. The first windows include pulse sequences have varying characteristics, such as increasing echo spacing, while the second windows preferably utilize similar pulse sequences which have very small echo spacing. Apparent internal field gradient distribution and apparent diffusion coefficient may be determined as a function of T2 relaxation time. These properties are readily visualized in a two-dimensional map with a first axis being the apparent internal field gradient or alternatively the diffusion coefficient of pore fluids, a second axis being the T2 relaxation times, and the vertical amplitudes being proportional to the proton population. Other properties which may be determined from use of this method include porosity, pore size distribution, oil and water saturation, oil viscosity, oil wettability, and permeability. Also, a method for determining and plotting a T1-MAS 2D spectrum is provided where T1 relaxation time and chemical shift are plotted on x,y axes while intensity of proton population is displayed along a third axis.
Owner:CHEVRONTEXACO US

Method for measuring oil content and water content in drilling fluid through low-field nuclear magnetic resonance

ActiveCN105223221AAccurate Analysis TestRapid analysis testAnalysis using nuclear magnetic resonanceManganeseLow field nuclear magnetic resonance
The invention discloses a method for measuring the oil content and the water content in drilling fluid through low-field nuclear magnetic resonance. Manganese chloride is used so that the relaxation time of water can be shortened, however, the relaxation time of oil is not affected, hence, the oil and the water in the drilling fluid can be distinguished, and quantitative testing of the oil content and the water content in the drilling fluid is achieved. The method includes the steps that nuclear magnetic resonance analysis is conducted on an original sample of the drilling fluid first, and the T2 relaxation spectrum of the original sample of the drilling fluid is tested; then a manganese chloride solution is added into the original sample of the drilling fluid to be fully stirred; afterwards, nuclear magnetic resonance analysis of the manganese-saturated drilling fluid is performed; the peak area of crude oil is the peak area of the manganese-saturated drilling fluid after the relaxation time is 1 ms, the peak area of the water in the drilling fluid is the difference between the peak area before manganese saturation and the peak area of the crude oil, and the peak area of the crude oil and the peak area of the water in the drilling fluid are introduced into corresponding working curve equations so that the oil content and the water content in the drilling fluid can be obtained; at last, the oil content and the water content of the drilling fluid can be obtained by combining the mass of the drilling fluid.
Owner:SUZHOU NIUMAG ELECTRONICS TECH

Tumor-targeted T1-T2 double nuclear magnetic resonance imaging contrast agent and preparation method and application thereof

The invention relates to a tumor-targeted T1-T2 double nuclear magnetic resonance imaging contrast agent and a preparation method and an application thereof. The contrast agent comprises hyaluronic acid-coated ferroferric oxide composite magnetic nanoparticles, wherein the molecular formula of hyaluronic acid is as shown in the specification; n is an integer of 17-290. The preparation method of the contrast agent comprises the following steps: (1) dissolving hyaluronic acid into deionized water, introducing a gas, and heating to obtain a reaction system A; (2) dissolving ferric salt and ferrous salt into a strong acid to obtain a solution B; (3) injecting the solution B into the reaction system A, adjusting the pH to be alkaline, and then refluxing at a high temperature to obtain a reaction system C; and (4) cooling a reaction system C to a room temperature, and dialyzing to obtain the contrast agent. The invention further provides an application of the contrast agent in T1 and T2 weighted imaging in in-vivo and in-vitro nuclear magnetic resonance. The contrast agent provided by the invention has superparamagnetism and outstanding T1 and T2 relaxation enhancement effects, and is suitable for being used as a T1-T2 double nuclear magnetic resonance imaging contrast agent.
Owner:THE NAT CENT FOR NANOSCI & TECH NCNST OF CHINA

Rapid evaluation method for rock core wettability change caused by nanometer fluid

The present invention relates to a rapid evaluation method for rock core wettability change caused by a nanometer fluid, wherein the T2 relaxation times of water before and after treatment of rock core with a nanometer fluid are tested by using special rock core nuclear magnetic resonance equipment, and the T2 cutoff value and the change thereof are determined so as to rapidly determine the rock core wettability change. The concrete method comprises: saturating rock core with water, and testing a T2 relaxation spectrum; removing movable water from the rock core through a centrifugal method and a gas flooding method, testing the T2 relaxation spectrum of pore wall bound water, and respectively accumulating the two T2 relaxation times to obtain the T2 spectrum accumulation curve of the saturated water and the T2 spectrum accumulation curve of the bound water; making a straight line parallel to the horizontal axis by using the maximum value of the T2 spectrum accumulation curve of the bound water, and making the straight line and the T2 spectrum accumulation curve of the saturated water intersect to obtain a T2 cutoff value; and determining the rock core wettability change through the change of the T2 cutoff value. According to the present invention, the process is simple, the evaluation is rapid, the injection of crude oil during the detection process is not required, and the secondary use of the rock core is not affected.
Owner:SHANGHAI UNIV

Testing method of specific surface area of particulate matter in suspension system

The invention discloses a testing method of the specific surface area of a particulate matter in a suspension system. The testing method comprises the following steps: (1) carrying out nuclear magnetic resonance detection on a solvent, controlling the temperature of the solvent by virtue of a metal bath, carrying out CPMG impulse sequence testing on the solvent to obtain T2 relaxation time of the solvent, and calculating relaxation rate R2f of the solvent; (2) adding a particulate matter sample into the solvent, so as to obtain suspension liquid containing the particulate matter sample; (3) carrying out the nuclear magnetic resonance detection on the suspension liquid containing the particulate matter sample, controlling the temperature of the suspension liquid by virtue of the metal bath, carrying out the CPMG impulse sequence testing on the suspension liquid to obtain T2 relaxation time of the particulate matter sample, and calculating the average relaxation rate according to a formula: R2=PbR2b+PfR2f; and (4) calculating the specific surface area of the particulate matter according to the following formula: Sa=(R2sp*R2f)/(Psi*Kp). According to the testing method, the specific surface area of the particulate matter in a suspension state can be tested.
Owner:SHANGHAI NIUMAI ELECTRONICS TECH

Evaluation method of mobile oil ratio and mobile oil source quantity of low porosity and low permeability sandstone reservoir

The invention discloses an evaluation method of the mobile oil ratio and the mobile oil source quantity of a low porosity and low permeability sandstone reservoir. The evaluation method comprises thefollowing steps of (A) acquiring oil-gas geology data of a target layer of an evaluation region; (B) performing sampling at different depths of the target layer of the evaluation region to obtain twoor more rock core samples, and determining the porosity and the permeability of each rock core sample; (C) adopting a low porosity and low permeability sandstone reservoir mobile oil ratio evaluationmethod to determine the mobile oil ratio of each rock core sample; (D) according to the porosity, the permeability and the mobile oil ratio of each rock core sample, establishing a relationship formula of the porosity, the permeability and the mobile oil ratio, and calculating the reservoir mobile oil ratio; and (E) calculating the mobile oil source quantity of the target layer of the evaluation region according to the reservoir mobile oil ratio. The mobile oil ratio calculation method provided by the invention does not need to consider a T2 relaxation time cutoff value and is higher in reliability by calculating the mobile oil ratio according to nuclear magnetic resonance T2 spectrum changes of the rock core samples before displacement and after displacement.
Owner:CHENGDU NORTH OIL EXPLORATION DEV TECH

Nano magnetic resonance imaging contrast agent and preparation method thereof

The invention relates to a nano magnetic resonance imaging contrast agent and a preparation method thereof. The contrast agent consists of external aqueous phase and humic acid substance-modified super-paramagnetic ferrite nano crystal dispersed in the external aqueous phase. The super-paramagnetic ferrite nano crystal is synthesized by adopting a chemical co-precipitation method, and the grain diameter is 15 to 30 nanometers. The nano crystal is purified and then dispersed in the external aqueous phase to form the contrast agent for intravenous injection. The contrast agent can be stabilized for over two years. The contrast agent has low toxicity, good biocompatibility, large time window and high saturation magnetization, and the half-life period of the contrast agent in the blood reaches 30 to 60 minutes. The contrast agent is absorbed by netlike endothelial systems in liver and spleen tissues through intravenous injection, and is focused in the liver and spleen tissues so as to shorten the T2 relaxation time. In a T2 image, signals of normal liver and spleen tissues are obviously reduced, and signals of tumor or pathological change tissues have no obvious change, so the contrast agent improves the imaging contrast of the focus and the normal tissue and can be used for early diagnosis of pathological changes such as micro tumor of liver and spleen tissues and the like.
Owner:HUNAN UNIV

Core oil/water calibration method based on nuclear magnetic resonance transverse relaxation spectrum line

The invention relates to a core oil/water calibration method based on a nuclear magnetic resonance transverse relaxation spectrum line (see Fig. 1 for the block diagram of the operation procedure). According to the method, in the process of saturating a core with oil/water before a core flooding experiment, the corresponding relationship between the oil/water mass or volume in the core and the peak area of a nuclear magnetic resonance T2 relaxation signal is tested, that is, a more accurate calibration result of the oil/water mass or volume and the signal amplitude is obtained without affecting the experimental operation procedure, so that the calibration is achieved. By using the calibration result, the change of the oil/water mass or volume in the core can be directly obtained by testingthe T2 relaxation spectrum line in the core flooding process, and the mass/volume and the recovery ratio of the produced oil/water can be further determined. According to the scheme of the invention,the key information of a nuclear magnetic resonance core flooding experiment is calibrated in real time based on the nuclear magnetic resonance T2 relaxation spectrum and the actual core flooding experiment, so that the accuracy and reliability of the experimental data can be improved, and the interference to the subsequent core flooding experiment cannot occur.
Owner:SHANGHAI UNIV

Method for nondestructively testing trepang autolysis on basis of nuclear magnetic resonance technique

The invention provides a method for nondestructively testing trepang autolysis on basis of a nuclear magnetic resonance technique. The method comprises the following steps: carrying out nuclear magnetic resonance signal collection on the trepang under the same parameters by adopting a magnetic resonance imaging analyzer and utilizing a CMPG sequence, thereby acquiring a transverse relaxation spectrum; and then judging the change of the content of free water in the trepang according to the degree of left shifting of T2 relaxation peak. According to the method for analyzing the water content change in the trepang autolysis process through low-field nuclear magnetic resonance provided by the invention, the transverse relaxation time spectrum T2 and the magnetic resonance imaging of the fresh bowel-cut trepang are taken as main analyzing basis, so as to quickly judge the water content change in the trepang autolysis process. The method provided by the invention has the advantages that the accuracy of the measuring result is high, the consumed time is short, the sample is free from being damaged, the inner visible information of the sample can be supplied, and the like. The reliable information is supplied to the detection for the autolysis process of the bowel-cut trepang and the change in the quality during the autolysis process of the bowel-cut trepang.
Owner:DALIAN POLYTECHNIC UNIVERSITY
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