7results about "Hydrogen phosphides" patented technology

The utility model provides a production device of electronic-grade hydrogen phosphide. The production device comprises a full-automatic aluminum phosphide feeding system, a sulfuric acid metering tank, a constant-temperature reaction kettle, a purification cooling system, a heavy component removal purification column, a cold trap collection device, a light component removal purification column, a low-temperature filling system, an inert gas purging system, a vacuum system and a tail gas treatment system. The method comprises the following steps: quantitatively adding aluminum phosphide into a constant-temperature reaction kettle, slowly adding sulfuric acid into the constant-temperature reaction kettle through a metering tank, reacting to generate hydrogen phosphide gas, and removing particulate matters, acid mist, moisture, arsenic hydride, hydrogen sulfide, carbon dioxide, carbon monoxide, alkane, silane and ethylene in the hydrogen phosphide gas through pre-cooling, deep cooling, heavy component removal, cold trap and light component removal to obtain the electronic-grade hydrogen phosphide special gas with the purity of 99.9999%. And feeding tail gas generated in the purification process into a tail gas treatment system, absorbing the tail gas through a two-stage tower, and discharging the tail gas after reaching the standard.

The application belongs to the field of organic phosphorus chemistry and phosphorus chemical industry, and particularly relates to a preparation method of phosphine. The method comprises the following steps: adding P4, Bu3SnH, a free radical initiator and an organic solvent into a test tube with a plug, sealing the test tube, wrapping the test tube with aluminum foil to avoid light, and stirring the test tube for a period of time; and then adding an acid into the reaction mixture to obtain phosphine. The application has mild reaction conditions, good safety and is suitable for industrial production.

The invention provides a method for producing electronic-grade phosphine by using sodium hypophosphite byproduct tail gas. The method comprises the working procedures of sodium hypophosphite tail gas purification, industrial phosphine pretreatment, anhydrous phosphine deep purification, phosphine catalytic decomposition, high-purity red phosphorus preparation and the like. The method is characterized by comprising the following steps: firstly, spraying and washing by-product tail gas generated in the production of sodium hypophosphite by using organic solvents such as carbon disulfide, then sufficiently filtering by using a sintered filter element with the precision of 1 micron, and carrying out two-stage cryogenic treatment to obtain industrial-grade hydrogen phosphide; performing four-stage adsorption on the industrial-grade phosphine to remove moisture, acetylene, ethylene and hydrogen sulfide, fully filtering by adopting a three-stage filter with the filtering precision of 1 micron, 10 nanometers and 3 nanometers, and removing particulate matters to obtain anhydrous phosphine; and finally, reducing the rest heavy components, light components and metal ions to below 10ppb through three-stage rectification to obtain the electronic-grade phosphine.

The application discloses a device for preparing electronic-grade sodium hypophosphite dearsenicated salt sodium salt, and belongs to the technical field of electronic chemical preparation. The device realizes the efficient dispersion of phosphine gas into micron-sized bubbles through a membrane dispersion reaction system, realizes the full and stable reaction of the phosphine gas with sodium hypochlorite solution, guarantees the high efficiency and uniformity of the main synthesis reaction from the source, and provides a composition-stable crude product liquid for subsequent continuous purification. Through a bypass arsenic removal unit integrated in a buffer adjustment system, the on-line circulation oxidation-precipitation-separation of arsenic impurities is realized without interrupting the main synthesis process, and the problem of the interruption of the synthesis route caused by the intermittent arsenic removal in the traditional process is solved. By arranging yellow phosphorus storage tanks in parallel and alternately working, the continuous and stable supply of the raw material yellow phosphorus to the phosphine reaction kettle is realized. The device ensures the long-term continuous and stable operation of the synthesis route and the high consistency of product batches, and is particularly suitable for the large-scale continuous production of electronic-grade sodium hypophosphite.

The utility model discloses a deliquescence type hydrogen phosphide gas generating device. According to the technical scheme, the phosphine generating device comprises a plurality of phosphine generating chambers, the phosphine generating chambers are fixed together through a top fixing plate and a bottom fixing plate, and each phosphine generating chamber comprises a keel mechanism playing a supporting role. A generating mechanism for generating phosphine gas, a material closing mechanism for preventing powder from falling and a powder collecting mechanism for collecting the powder are fixedly arranged in the keel mechanism, and a dust isolation mechanism for sealing the phosphine generating chamber is further arranged outside the keel mechanism. The scheme provided by the utility model is used for generating hydrogen phosphide gas, that is, the hydrogen phosphide gas is fully subjected to deliquescence reaction with moisture in flowing air, and residues are automatically fed into the treatment unit, so that the contact between people and medicines and the contact between the medicines and the environment are minimized, the harm of toxic gas in the environment is reduced, and the personal safety is ensured.

The utility model provides a device for producing ultrapure phosphorane through differential pressure thermal coupling rectification. A first condensation reflux device is arranged at the top of a first rectifying tower, and a first reboiler is arranged at the bottom of the first rectifying tower; a second condensation reflux device is arranged at the top of the second rectifying tower, and a second reboiler is arranged at the bottom; the top of the first rectifying tower is sequentially connected with a second reboiler, a first condensation reflux device and a second rectifying tower through a conveying pipeline; a third condensation reflux device is arranged at the top of the third rectifying tower, and a third reboiler is arranged at the bottom; the bottom of the second rectifying tower is connected with the third rectifying tower. A diaphragm compressor is arranged at the top of the third rectifying tower, the pressure of a product is increased, normal-temperature filling can be guaranteed, and meanwhile, an outlet of the diaphragm compressor is connected with a first reboiler B, so that heat of a gas phase at the top of the third rectifying tower is fully utilized. The system and the device can effectively remove impurities such as H2O, O2, H2, C2H6, CH4, CO, SiH4, C2H4 and AsH3 in industrial hydrogen phosphide to obtain electronic-grade hydrogen phosphide; meanwhile, the energy consumption in the operation process is reduced, and the annual operation cost is reduced.

The present invention relates to a system (10) and for safe generation of phosphine gas. The present invention also relates to a process for generating phosphine gas in the presence of CO2 for limited period. The system includes a reaction pot (12) configured to receive metal phosphide (14) and water as an input. The metal phosphide (14) and water react to generate phosphine gas. Further, the system includes an air compressor (18) fluidly coupled to the reaction pot. The air compressor is configured to supply pressurized air to the reaction pot to agitate the mixture of metal phosphide (14) and water. Furthermore, the system includes a carbon dioxide supply unit (40) fluidly coupled to the reaction pot and configured to supply carbon dioxide gas to the reaction pot to maintain phosphine gas concentration below 5000 ppm to prevent fire hazard.