This invention relates to the field of photopolymerization materials technology, and more particularly to a low-migration,
oxygen-resistant
photoinitiator, its preparation method, and applications, applicable to
environmentally friendly coatings, 3D printing resins, and biomedical adhesives. The nano-
photoinitiator of this invention is prepared from a trivalent iron salt compound and an organic ligand containing a
carboxylic acid group; it generates initiating free radicals under
ultraviolet and / or
visible light irradiation, which are used to initiate the free
radical polymerization reaction of unsaturated monomers. The
system of this invention can still achieve rapid and complete curing in an air environment, significantly reducing or avoiding the
oxygen inhibition effect commonly found in traditional free radical photocuring, and exhibits high stability; simultaneously, it has advantages such as wide availability of raw materials, low cost, easy aqueous
phase conversion, and reduced potential
irritation and migration risks, thus improving the
system's
biocompatibility and environmental friendliness.