The invention discloses a coal gasification phenol water pollution-free circulation treatment method. According to the present invention, the treatment process is based on a special treatment apparatus; the special treatment apparatus comprises a catalytic oxidation pool, an oxidation stabilization pool, a post-biochemical BAF pool, a clear water pool, a dilution comprehensive tank, a pretreatmentfirst-stage BAF pool, a pretreatment second-stage BAF pool and an effluent pool, wherein the catalytic oxidation pool, the oxidation stabilization pool, the post-biochemical BAF pool and the clear water pool are sequentially connected through a rear-section transmission pipeline, ozone catalytic particles comprise active alumina particles, copper oxide, titanium dioxide, polyethylene glycol and polyvinyl alcohol, and a carrier comprises, by weight, high-density polyethylene, a polypropylene resin, slaked lime, Dow powder active carbon, light calcium carbonate, maleic anhydride, gelatin, chitin, ferroferric oxide magnetic powder and manganese-zinc ferrite; and with the coal gasification phenol water pollution-free circulation treatment method, the good effects of wastewater COD removal, decolorization, deodorizing, toxic pollutant degradation and wastewater biodegradability improving can be provided.