Conductive catalytic particles which are composed of a conductive
powder and a catalytic material adhering to the surface thereof. The catalytic material is an
alloy of a
noble metal material with an additive material which is thermally
solid-insoluble in said
noble metal material, or an
alloy of MI and MII (where MI denotes at least one species selected from
noble metal elements, and MII denotes at least one specifies selected from Fe, Co, Ni, Cr, Al, Cu, Hf, Zr, Ti, V, Nb, Ta, W, Ga, Sn, Ge, Si, Re, Os, Pb, Bi, Sb, Mo, Mn, O, N, C, Zn, In, and
rare earth elements). The conductive catalytic particles are produced by causing the noble
metal material and the additive material or MI and MII to adhere at the same time to the surface of a conductive
powder by
physical vapor deposition. The conductive catalytic particles are not liable to
sintering and are used for a gas-diffusing catalytic
electrode and an electrochemical device provided therewith.