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34 results about "Methidathion" patented technology

Methidathion is an organophosphate insecticide; its use is banned in the European Union and USA. Methidathion has been used as an insecticide in many countries to control caterpillars of Indarbela quadrinotata.

Degrading method of pesticide residues in ginseng oral liquid by utilizing radiation

The invention provides a degrading method of pesticide residues in ginseng oral liquid by utilizing radiation, and belongs to the technical field of pesticide residue degrading treatment in Chinese herbal medicines. The method is to treat the ginseng liquid containing multiple pesticides (methidathion, fonofos, diazinon, phosalone, imidacloprid, fenpropathrin totally six forbidden or restricted pesticides) by adopting an electronic accelerator which produces high-energy electrons in the radiation condition, so that the pesticides are degraded, wherein the energy of the electron accelerator is7.5MeV and the electron radiation dose is between 2 and 15kGy; and concentrations of the six pesticides are detected by an ultra-high performance liquid chromatography-tandem mass spectrometer after radiation so as to determine the degrading effect. By adopting the method, residues of the six pesticides in the ginseng oral liquid can be reduced or eliminated efficiently, quickly and safely, and the degrading rates of the six related pesticides are over 30 percent in 15kGy radiation, so that the limit standard of European Union and other countries can be achieved. The degrading method providesa good idea for degrading of pesticides in ginseng oral liquid, and has wide development prospect.
Owner:ANIMAL & PLANT & FOOD INSPECTION CENT OF TIANJIN ENTRY EXIT INSPECTION & QUARANTINE BUREAU

Method for preventing and curing grape scale insects

The invention discloses a method for preventing and curing grape scale insects, the method comprises the steps that during winter pruning, the trunk and the aged raised skin are subjected to skin scrapping with a clean skin scraper, dry branches and fallen leaves are cleared and old skin is stripped, overwintering egg mass is brushed away, and centralized burning is performed; then a whitening agent containing methidathion is used for whitening the trunk so as to clear and kill orchard germs and worm eggs and reduce the next year disease and insect cardinal numbers; before the beginning of spring, insect glue is smeared to the trunk, and a closed glue ring with the width of 3-5 cm is smeared on the trunk to prevent overwintering insects to climb the tree; lime sulphur with 3-5 baume degreeis sprayed in the whole orchard in the spring grape pompon period; a 24% of spirotetramat 5,000 times solution or 40% of chlorpyrifos 1,500 times solution is sprayed to the whole plant in the last ten-day of May. With the adoption of the method, the scale insects can be basically killed thoroughly and can be effectively prevented from climbing to the tree to damage the grape, the pesticide is sprayed in last ten-day of May and washed or degraded clean before the grape is mature, and the pesticide residue doesn't exceed the standard.
Owner:ZHENGZHOU FRUIT RES INST CHINESE ACADEMY OF AGRI SCI

Degrading method of pesticide residues in ginseng oral liquid by utilizing radiation

The invention provides a degrading method of pesticide residues in ginseng oral liquid by utilizing radiation, and belongs to the technical field of pesticide residue degrading treatment in Chinese herbal medicines. The method is to treat the ginseng liquid containing multiple pesticides (methidathion, fonofos, diazinon, phosalone, imidacloprid, fenpropathrin totally six forbidden or restricted pesticides) by adopting an electronic accelerator which produces high-energy electrons in the radiation condition, so that the pesticides are degraded, wherein the energy of the electron accelerator is 7.5MeV and the electron radiation dose is between 2 and 15kGy; and concentrations of the six pesticides are detected by an ultra-high performance liquid chromatography-tandem mass spectrometer after radiation so as to determine the degrading effect. By adopting the method, residues of the six pesticides in the ginseng oral liquid can be reduced or eliminated efficiently, quickly and safely, and the degrading rates of the six related pesticides are over 30 percent in 15kGy radiation, so that the limit standard of European Union and other countries can be achieved. The degrading method provides a good idea for degrading of pesticides in ginseng oral liquid, and has wide development prospect.
Owner:ANIMAL & PLANT & FOOD INSPECTION CENT OF TIANJIN ENTRY EXIT INSPECTION & QUARANTINE BUREAU

Method for detecting residual methidathion in ripe orange

The invention discloses a method for detecting residual methidathion in a ripe orange. The method for detecting residual methidathion in the ripe orange comprises the following steps: (1) dividing a ripe orange into an orange peel part and a pulp part, cutting the orange peel into pieces, and squeezing pulp with a juice extractor to obtain juice for later use; (2) respectively putting the orange peel and pulp into conical flasks, respectively adding acetonitrile water mixed liquor, and carrying out vibrating extraction for 50-70 minutes; respectively carrying out suction filtration to obtain clear liquids; concentrating the clear liquids respectively, and realizing constant volume being 10ml again by adopting water, so as to obtain an orange peel sample and a pulp sample for later use; (3) putting neutral aluminium oxide powder into a muffle furnace, activating for 4 hours at the temperature of 680 DEG C, packing, firstly passing a column with 20ml acetonitrile, loading the samples, firstly activating a small column with 10ml mixed liquor of acetonitrile and water in a volume ratio of 1:1, then leaching with 20ml acetonitrile, collecting leacheate, carrying out rotary evaporation until volume of the leacheate is 1ml, blow-drying with nitrogen, realizing constant volume being 5ml by adopting acetone, and making preparation for detection; (4) detecting by adopting a gas chromatography.
Owner:SUZHOU APP SCI ACAD CO LTD

A kind of detection method of the residues of methapon in ripe oranges

The invention discloses a method for detecting residual methidathion in a ripe orange. The method for detecting residual methidathion in the ripe orange comprises the following steps: (1) dividing a ripe orange into an orange peel part and a pulp part, cutting the orange peel into pieces, and squeezing pulp with a juice extractor to obtain juice for later use; (2) respectively putting the orange peel and pulp into conical flasks, respectively adding acetonitrile water mixed liquor, and carrying out vibrating extraction for 50-70 minutes; respectively carrying out suction filtration to obtain clear liquids; concentrating the clear liquids respectively, and realizing constant volume being 10ml again by adopting water, so as to obtain an orange peel sample and a pulp sample for later use; (3) putting neutral aluminium oxide powder into a muffle furnace, activating for 4 hours at the temperature of 680 DEG C, packing, firstly passing a column with 20ml acetonitrile, loading the samples, firstly activating a small column with 10ml mixed liquor of acetonitrile and water in a volume ratio of 1:1, then leaching with 20ml acetonitrile, collecting leacheate, carrying out rotary evaporation until volume of the leacheate is 1ml, blow-drying with nitrogen, realizing constant volume being 5ml by adopting acetone, and making preparation for detection; (4) detecting by adopting a gas chromatography.
Owner:SUZHOU APP SCI ACAD CO LTD
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