The invention discloses stable
selenol and poly (selenourethane) thereof, preparation and
recovery methods and application,
selenol is stable micromolecules with at least two degrees of functionality, and poly (selenourethane) is prepared by directly participating in
polymerization of
selenol. The selenol overcomes the limitation that
selenium-containing small molecules are unstable in the environment, and the polyselenourethane has rich and adjustable performance, is stable in structure, simple in preparation method, high in
reaction speed, few in
side reaction in the
polymerization process, high in molecular weight, suitable in polydispersity coefficient and excellent in optical performance, and can be applied to the field of electronic devices. Good mechanical properties are achieved in room-temperature and low-temperature environments; meanwhile, the polyselenourethane has good thermal responsiveness and
oxygen responsiveness,
chemical recovery of selenol can be achieved under the simple heating condition, the polyselenourethane can be degraded by reacting with
oxygen,
active oxygen and the like in the service environment, meanwhile,
selenium-containing components capable of being biologically utilized are released, and the
selenium-containing components can be recycled. And a new opportunity is provided for development of organic selenium
chemistry and selenium-containing polymers and internal and
external application of organisms.