A kind of sodium ion battery multiple positive electrode material and preparation method thereof: the chemical general formula of this sodium ion battery multiple positive electrode material is Na 0.67 mn x Mg y Ni z W n o 2‑q B q , wherein, 0.65≤x≤0.8, 0<y≤0.2, 0<z≤0.2, 0<n≤0.2, 0<q≤0.05, x+y+z+n=1. The preparation method firstly adds sodium source, manganese source, nickel source, magnesium source, tungsten source and boron source into citric acid to generate a sol, then dries the sol to obtain a gel, and heat-treats the gel to obtain the multi-component sodium ion battery. Cathode material. The preparation of multi-element cathode materials for sodium ion batteries utilizes cation or anion doping or co-doping to enhance the structural stability and conductivity of the material. The material has good rate performance and excellent cycle stability, and the required raw material resources are abundant, the cost is low, and the preparation method is simple and controllable.