The invention discloses a free radical advanced oxidation reactor, which comprises a reactor body, an ultraviolet lamp and an aeration device, wherein the reactor body is a closed vessel; a water inlet, a water outlet, a medicine feeding port, an ozone inlet and an end gas outlet which are communicated with the inside of the reactor body are arranged on the reactor body respectively; the ultraviolet lamp and the aeration device are both arranged inside the reactor body; the ultraviolet lamp adopts at least two groups of medium voltage fluorescent lamps with different wavelengths, and the aeration device is communicated with the ozone inlet on the reactor body. The reactor has the advantages of simple structure, strong capability of treating difficultly biodegraded organic matters, short reaction time, high reaction efficiency, wide application range, simple operation, stable outputted water quality, no secondary pollution, joint use with other water treatment methods, and the like. The reactor can be used as an advanced treatment reactor for a slightly polluted water body or a pretreatment reactor for a high-concentration organic polluted water body.