The invention relates to a
perovskite battery based on a co-doped
nickel oxide-based
hole transport layer and a preparation method of the
perovskite battery. The
perovskite battery sequentially comprises a conductive substrate, a
hole transport layer, an
ionic liquid modification layer, a perovskite
active layer, an
electron transport layer, a hole
barrier layer and a
metal electrode layer from bottom to top, and the
hole transport layer is a Li-Nb co-doped
nickel oxide thin film. According to the invention, by introducing the Li and Nb elements, the hole concentration and mobility can be synergistically improved, the
energy level arrangement can be optimized, the morphology and
crystallinity of the thin film can be improved, the problems of insufficient
conductivity, energy band mismatch, interface recombination and the like of NiO-based HTL can be solved, and finally, the
perovskite solar cell with higher efficiency, stability and reliability can be realized. The
ionic liquid modification layer is also introduced, so that the interface contact between the thin film and the perovskite material can be improved, the contact
side reaction is inhibited, and the service life of the perovskite battery is prolonged.