The invention provides a railway carriage antifreezing solution and its preparing method, including the following components in weight precent: anhydrous calcium chloride 20-50%, alcohol 8-10%, and water 40-70%, and it can also adds in antirusting agent sodium nitrite in 1-2%. The preparing method: firstly adding water in a stirring jar, then adding in the anhydrous calcium chloride and stirring to fully dissolving them, eliminating foam, then stirring to the temperature at 19 deg.C-21 deg.C, adding in alcohol, adding in the antirusting agen, stirring for 30 minutes and then ending. It can ensure the vehicle skins do not freeze with the hydrous bulk materials in 10 hours in the open air, and thoroughly solves the freezing problem of the iron mine powder-like hydrous bulk materials in the winter, thus need not defreeze them in defreezing rooms to smoothly discharge, saving energy sources, shortening turnover cycle of railway carriages, reducing labor strength and reducing transport cost.