The invention provides an application method of a battery utilizing a
lithium-rich
manganese-based
solid solution material as a positive
electrode. The method comprises the following steps: performing electrochemical charging and discharging activation treatment on the battery utilizing the
lithium-rich
manganese-based
solid solution material as the positive
electrode; performing charging and discharging circulation on the activated battery, wherein the
cut-off
voltage of the battery subjected to charging and discharging circulation is less than the charge
cut-off
voltage during the activation treatment. According to the method provided by the invention, the
lithium-rich
manganese-based
solid solution material releases full capacity by virtue of activating, a layer structure is transformed into a
spinel structure quickly, and then the battery can be subjected to charging and discharging circulation in a mild condition, and the material still has higher capacity under a lower charging
cut-off
voltage. Meanwhile, in the mild condition, the un-removed lithium
ion plays a role in supporting the structure, so that the lithium-rich manganese-based
solid solution material keeps a stable structure in the process of electrochemical
cycling, without obvious voltage falling, and thus voltage attenuation is restrained effectively.