The invention discloses a
lithium-rich
manganese-based ternary composite precursor, a positive
electrode material and a preparation method of the positive
electrode material, and the positive
electrode material is spherical or sphere-like particles, is formed by compounding three
layers of materials, and comprises an inner core, a
transition layer and a shell. The preparation method of the positive
electrode material comprises the following steps: mixing a first
nickel salt, a first
cobalt salt, a first
manganese salt, a first aluminum salt and an M2 salt to obtain a first
metal liquid; second
nickel salt, second
cobalt salt, second
manganese salt, second aluminum salt and M3 salt are mixed to obtain second
molten metal; the first
molten metal and the second
molten metal are mixed to form third molten
metal; carrying out a first mixing reaction to obtain a manganese-rich
hydroxide core; forming a
transition layer outside the inner core through a second mixing reaction; forming a ternary
hydroxide shell outside the
transition layer through a third mixing reaction to obtain a precursor; and mixing the precursor with a
lithium source, and
sintering to obtain the positive
electrode material. The
lithium ion diffusivity of the whole material can be remarkably improved, and the
thermal stability, the first efficiency, the cycle performance and the rate capability of the material are remarkably improved.