72results about How to "Thickening time adjustable" patented technology

The invention relates to a high-temperature-resistant non-silicate cement paste system for cementing a thermal production well for thickened oil. The high-temperature-resistant non-silicate cement paste system is composed of the following components in parts by weight: 100 parts of high-temperature-resistant cement, 1.0-4.0 part(s) of fluid loss agent, 1.0-4.0 part(s) of dispersant, 0.5-3.0 part(s) of thickening time control agent, 60-120 parts of water and 15-80 parts of heat regulators, wherein the high-temperature-resistant cement is formed by mixing components A and B, the component A comprises 50-77 parts of Al2O3, 0.5-8.0 part(s) of SiO2, 0.5-2.5 part(s) of Fe2O3 and 0-0.4 part of R2O(Na2O+0.658K2O), and the component B comprises 33-63 parts of 3CaO.Al2O3.CaSO4, 14-37 parts of 2CaO.SiO2 and 15-35 parts of 6CaO.Al2O3.2Fe2O3. The high-temperature-resistant non-silicate cement paste system disclosed by the invention has great significance to enhancement of safe and efficient development of the thickened oil and has broad market prospect.

The invention relates to well-cementing and self-healing cement slurry for an oil-gas field, which is suitable for the field of oil well cementation. The well-cementing and self-healing cement slurry comprises the following additives percentage by weight: 2-4% of fluid loss agent, 5-40% of self-healing component, 0.2-1.0% of stabilizing agent, 0.5-2.0% of dispersing agent, 0.3-1.0% of de-foaming agent, and 0.03-0.5% of retarding agent by taking the weight of cement as benchmark. A preparation method of the well-cementing and self-healing cement slurry is as follows: controlling the water cement ratio to be 0.44, uniformly mixing the additives at a low shearing speed, weighing a certain amount of cement, adding into slurry preparation liquid, and mixing with API (American petroleum institute) standards to obtain the well-cementing and self-healing cement slurry. The well-cementing and self-healing cement slurry has the characteristics of low water loss, adjustable thickening time, gas channeling prevention and excellent impervious performance and the like, has the functions of crack prevention and self healing, and remarkably improves the mechanical property of the cement.

The invention discloses an oil well cement flexibilizer. The oil well cement flexibilizer can be used as an admixture for oil well cement of oil-gas well cementing, and is prepared from the following components in parts by mass: 15-50 parts of a temperature-resistance rubber material, 0-20 parts of surface modified fibers, 10-20 parts of a stabilizer and 10-50 parts of a rheolobic modifier. The flexibilizer can be used for reducing the elasticity modulus of annulus set cement and improving the impact resistance of set cement, and is well compatible with other cement admixtures. The flexibilizer has stable normal-temperature and high-temperature performances, and can be used for improving the rheological property of cement paste, solving the problem that the annulus set cement in an oil-gas well has poor stress resistance and cannot adapt to big-frac treatment in the oil and gas exploitation process, and prolonging the service life of the oil-gas well.

The invention relates to a cement paste toughening agent and application of the cement paste toughening agent in preparation of a cementing flexible cement paste. The toughening agent is prepared by modification of rubber powder; the modification of rubber powder includes the steps of cleaning, activating, etching and grafting; the cementing flexible cement paste prepared by the toughening agent is prepared from the following components in parts by weight: 100 parts of portland cement, 5-50 parts of modified rubber powder, 10-40 parts of a toughing agent, 15-80 parts of a density regulator, 35-65 parts of water, 0.5-2 parts of a dispersing agent, 0.5-3 parts of a fluid loss agent, 1.5-4 parts of a retarder and 0.1-2 parts of a defoamer. The inherent performance of a substrate is not changed by plasma treatment on the rubber powder; no pollution is generated; the cement paste toughening agent is simple in process, convenient to operate, stable in hydrophilism through the grafted rubber powder, small in effect from timeliness, and low in handling expense; the flexible cement paste prepared from the modified rubber is good in sedimentation stability; the mechanical property is obviously improved; the cement construction requirements of the scene can be completely met.

The invention discloses an oil-well cement leakage-proof toughener which not only has leakage-proof function and improves the toughness of cement rocks, but also has good multiple-purpose project performance, so as to have double effects and solve the technical problems of slurry loss and the inherent brittleness of the cement rocks in the process of well cementation; the oil-well cement leakage-proof toughener comprises the components based on the weight percentage: 5-30% of organic fiber material, 35-70% of special type inorganic fiber, 1.0-10% of organic polymer material, 5.0-15% of modifying agent and 1.0-10% of auxiliary material.

The invention relates to a high temperature ductility well cementing carboxylic styrene butadiene latex additive. The additive consists of 1 portion of a liquid A, 0.067 to 0.133 portion of a liquid B and 0.067 to 0.133 portion of a liquid C. The liquid A comprises 1 portion of carboxylic styrene butadiene latex, 0.03 to 0.3 portion of sulfonate, 0.0 to 0.8 portion of phosphate, carboxylate or a mixture thereof, and 0.1 to 0.8 portion of an acrylamide-acrylic acid-alpha-acrylamide-2-methylpropanesulfonic acid copolymer; the liquid B contains two nonionic surfactants and deionized water; and the liquid C contains two anionic surfactants and the deionized water. When a well bottom temperature reaches between 190 and 240 DEG C, cement slurry is also characterized in low water loss, adjustable thickening time and high compressive strength; and the hardened cement formed by the cement slurry can ensure good well cementing quality with ductility.

The invention provides high temperature resistant well cementation cement paste used for a steam injection thermal production well, and the cement paste comprises the following components by weight: 100 parts of high temperature resistant cement, 30-40 parts of a high temperature stabilizer, 0.5-1.2 parts of a thickening time control agent, 2.5-4.5 parts of an oilwell cement fluid loss agent, 0.02-0.15 part of an anti sedimentation agent, 0.02-0.15 part of a defoaming agent, and 45-100 parts of water. The high temperature resistant well cementation cement paste can effectively solve the problems of quick reduction in strength, fast rising in permeability and the like of well cementation cement paste systems in the prior art, can improve the thermal stability, reduces the possibility of channeling and casing damage, can make oilwells long-term sealed, improves production efficiency, and reduces production cost.

The invention discloses a cementing slurry with high temperature, high density and high toughness, which comprises the following ingredients by weight 100 parts of H grade oil well cement, 30-40 parts of silicon powder, 80-120 parts of a GM weighting agent, 0.6-0.8 parts of a suspending agent, 4-6 parts of a high temperature fluid loss reducer, 4.0-5.0 parts of a dispersant, 0.1 parts of an antifoaming agent, 5.0-6.0 parts of NaCl, 3 parts of latex and 57.35-59.72 parts of water. The density of the cementing slurry can reach 2.40-2.50gcm3, the cementing slurry can resist a temperature of 160 DEG C, and the cementing slurry has the advantages of good rheological property under high temperature, good settlement stability and good cement stone toughness, is suitable for cementing depth wellsand ultra-deep wells, and is in favor of improving the sealing quality and raising the quality of the wells.

The invention discloses well cementation cement paste with a high water-cement ratio, low cost and a low density. The well cementation cement paste is prepared from the following raw materials in parts by weight: 40 to 100 parts of oil well cement, 25 to 60 parts of coal ash, 30 to 40 parts of silica fume, 2 to 3 parts of an early strength agent, 2 to 8 parts of a ternary exciting agent, 3 to 3.5parts of a fluid loss agent, 0 to 0.2 part of a dispersing agent, 0.2 part of a defoaming agent and 180 to 272 parts of clean water, wherein the ternary exciting agent is a mixture of soda lime and magnesium sulfate, the mass ratio of the soda lime to the magnesium sulfate is 9 to 1, and the soda lime and the magnesium sulfate are both sieved by a 100-mesh sieve. Meanwhile, the invention further discloses a preparation method of the well cementation cement paste preparation method. The well cementation cement paste has low cost; after the ternary exciting agent is added, the compressive strength is improved, and a requirement of well cementation for the strength of low-density cement paste is met; furthermore, expansibility is improved, cement paste micro annular spaces caused by the inherent shrinkage character are reduced, and the risk of poor wellhole sealing safety is reduced.

The invention discloses a high-temperature high-density cement slurry for oil field high-temperature high-pressure well cementation and a preparation method thereof. The high-temperature high-density cement slurry includes oil well cement, a weighting agent, an anti-high temperature strength degradation agent, a stabilizer, a fluid loss agent, a dispersing agent, a retarder, a defoaming agent and the like. A particle gradation principle is employed in the invention, and the particle sizes and the dosages of various materials are optimized, thus achieving close packing of solid phase materials. A weighted blended slurry solution is mixed with the solid phase materials, secondary weighting is carried out on the cement slurry, and by cooperating with the regulation of an excellent performance high temperature salt resistant treatment agent, a high-temperature high-density liquid mixture with good comprehensive performance can be formed, thus solving the contradiction of influence between high-temperature high-pressure well cementation cement slurry density, high temperature resistance, rheological property and sedimentation stability.

The invention discloses a thermosetting epoxy resin well cementation working solution which is prepared from the following ingredients in parts by weight: 100 parts of bisphenol A type waterborne epoxy resin, 0.3 to 4.0 parts of an aliphatic amine curing agent, 0.2 to 4.0 parts of a flexibilizer, 0.1 to 3.0 parts of an ester diluent, 5.0 to 60 parts of a density modifier and 1 to 30 parts of water, wherein the flexibilizer is a mixture of modified carbon nanotube and modified magnesium borate crystal whisker according to a part-by-weight proportion of 0.2 to 3.0; the modified nanotube is prepared by a carbon nanotube surface modifying method, the carbon nano tube is oxidized at first, and the carbon nano tube is treated by sodium hypochlorite; the modified magnesium borate crystal whiskeris prepared by a magnesium borate crystal whisker coupling treatment method. The thermosetting epoxy resin well cementation working solution disclosed by the invention has the characteristics of hightensile strength, high rupture strength and good toughness, can be directly applied to oil gas well cementation, also can be applied to repairing of damaged cement sheaths on which micro cracks arre generated and has a wide market application prospect.

The invention discloses elastic modified resin for oil well cement. The elastic modified resin comprises the following raw materials in parts by weight: 100 parts of an epoxy resin-based solution and10-25 parts of an epoxy resin curing agent. The invention further discloses well cementation cement paste. The ell cementation cement paste comprises the following raw material s in parts by weight: 100 parts of cement, 36-44 parts of fresh water, 3-6 parts of a fluid loss agent, 0.1-0.6 part of a dispersing agent, 1-4 parts of an early strength agent, 2-5 parts of a reinforcing agent, 0.2-0.6 part of a retarder, 0.5-1.5 parts of a defoaming agent and 20-50 parts of elastic modified resin. According to the invention, the elastic modified resin is used as an admixture functional material for oil well cement and is mixed with the oil well cement for use, so the damage resistance of a cement sheath is enhanced, and the cement paste has the advantages of good stability, no sedimentation phenomenon, good fluidity, adjustable thickening time and low water loss, and meets the requirements of cementing construction operation.

The invention discloses an endogenous toughened corrosion-resistant cement mortar system which is composed of the following components in parts by weight: 100 parts of high-sulfate-resistance Grade-G oil well cement, 5-35 parts of microcrystal calcium aluminoferrite, 0-25 parts of micro silicon, 1.0-4.5 parts of water-loss control agent, 0.5-3.0 parts of dispersing agent, 0.2-3.0 parts of thickening time control agent and 44-80 parts of water. The microcrystal calcium aluminoferrite is prepared by high-temperature calcination and shock cooling. The micro silicon is a density regulator. The water-loss control agent is polyvinyl alcohol, polyacrylamide or carboxymethyl cellulose. The dispersing agent is sodium hexametaphosphate, melamine formaldehyde resin, sodium lignosulfonate or methyl cellulose. The thickening time control agent is boric acid, gypsum, sodium borate or a mixture thereof. The endogenous toughened corrosion-resistant cement mortar system has the advantages of excellent impact resistance, higher compression strength, high volume stability and small changes of porosity and permeability, has important meanings for ensuring safe and efficient development of shale gas, and thus, has broad market prospects.

The invention relates to the technical field of oil field well cementation, particularly to a frozen ground region negative-temperature well cementation cement slurry, a preparation method and applications thereof, wherein the frozen ground region negative-temperature well cementation cement slurry comprises, by weight, 100 parts of modified aluminate cement, 6-15 parts of a negative-temperature anti-freezing early strength agent, 0.05-3 parts of an alcohol-ammonia coagulant, 40-44 parts of water, 0-5 parts of a light metal expanding agent and 0-6 parts of a non-ionic polymer fluid loss agent.According to the invention, the frozen ground region negative-temperature well cementation cement slurry is good in rheological property, can be cured within 3 h at a temperature of -18 DEG C, has a24-h compressive strength of up to 6 MPa, can effectively solve the problems that cement is not cured and has no strength, the well cementation quality of the low-temperature frozen ground region is poor, and even well cementation operation cannot be completely conducted due to liquid-phase segregation ice condensation of the conventional cement slurry in a negative temperature environment, and meets the well cementation construction requirements of frozen ground regions.

The invention provides an ultrahigh-strength tough cement slurry system for well cementation and preparation and application thereof. The ultrahigh-strength tough cement slurry system for well cementation comprises the following raw materials: 100 parts by weight of cement, 20-40 parts by weight of a high-temperature reinforcing material, 0.5-6 parts by weight of an inorganic toughening material, 0.5-4 parts by weight of a suspension stabilizer, 2-6 parts by weight of micro silicon, 0.5-1.5 parts of a dispersing agent, 2-6 parts of a fluid loss agent, 1-8 parts of a retarder, 0.2-1 part of a defoaming agent and 40-60 parts of clear water. The cement paste system is good in flowability and sedimentation stability, low in water loss, adjustable in thickening time and wide in adaptive temperature range; the set cement has the characteristics of ultrahigh strength and the like, well cementation requirements of deep shale gas, high-temperature deep wells and the like can be well met, set cement strength decline caused by high-temperature strength can be avoided, and the service lifetime of an oil-gas well can be further prolonged.

The invention discloses a composite lightening material which comprises the following components in parts by weight: 100 parts of coal ash, 10-15 parts of expanding materials and 5-10 parts of toughening materials, wherein the particle size range of the coal ash is 5-10 microns. The invention also relates to a preparation method of the composite lightening material, and the preparation method comprises the following steps: i) carrying out smashing and ball milling on the coal ash through an overhang roll mill, classifying the smashed and ball-milled coal ash through a classifier, and collecting the coal ash with the particle size range of 5-10 microns after the classification to obtain modified coal ash; and ii) mixing the modified coal ash obtained in the step i) with the expanding materials and the toughening materials according to the proportion so as to obtain the composite lightening material. Meanwhile, the invention also discloses deep well composite cement paste and an application of the composite cement paste in well cementing of oil/gas wells.

The invention discloses a drilling and solidifying integrated working fluid for improving two-interface cementation quality, and an application method thereof, wherein the integrated working fluid comprises, by weight, 100 parts of a drilling fluid, 5-15 parts of a composite latent active cementing material, a suitable amount of a pH value adjuster for controlling the pH value of the integrated working fluid at 7-11 during drilling, and a suitable amount of an alkaline activator for controlling the pH value of the integrated working fluid at more than 12 during well cementing. According to the present invention, the mud cake formed by the drilling fluid and the solidified body of the cell cementing fluid are converted into the continuous integration by the high-strength active material, wherein the continuous integration is the drilling fluid during the drilling, and the mud cake containing the latent active material can be activated and solidified under the activation of the activator after the drilling is completed and the bushing is arranged so as to eliminate the sandwich cake effect and effectively improve the two-interface cementation quality; and the remaining drilling fluid after the completion of the well cementing can be solidified in situ, and the drilling and cementing integrated technology meets the drilling requirements of well depth of 5000 m, temperature of 150 DEG C and formation pressure of 2.0 g/cm<3>.

The invention discloses a modified polybenzimidazole fiber reinforcement cement paste system. The system comprises the following components in parts by weight: 100 parts of high sulfate resistance grade-G oil well cement, 0.2 to 3.0 parts of modified polybenzimidazole fiber, 0 to 40 pars of quartz sand, 0.5 to 2.5 parts of a dispersant, 1.0 to 6.0 parts of a fluid loss agent, 0.2 to 3.0 parts of aretarder, and 38 to 70 parts of water. The modified polybenzimidazole fiber is performed by performing surface modification on the polybenzimidazole fiber as follows: firstly, performing oxidation treatment on the polybenzimidazole fiber, then, performing low temperature plasma treatment on the polybenzimidazole fiber, and finally, performing coupling treatment on the polybenzimidazole fiber. Feinforcement cement paste has the characteristics of high tensile strength, breaking strength and low elasticity modulus, the modified polybenzimidazole fiber is high in temperature resistance capacityand good in dispersibility in cement paste, set cement is excellent in mechanical property, and the system has important application value for improving the cementing quality of high temperature deepwells and shale gas wells.

The invention discloses a low-temperature high-strength oil-gas well plugging agent, and relates to the technical field of petroleum drilling materials. The low-temperature high-strength oil-gas wellplugging agent is prepared from the following raw materials in percentage by mass: 70 to 90 percent of an inorganic gel material, 0 to 0.5 percent of a fiber toughening agent, 1 to 20 percent of a filling material, 1 to 5 percent of an expanding agent, 0.1 to 0.3 percent of a flocculating agent and 0.05 to 0.2 percent of a retarder, wherein the inorganic gel material is sulphoaluminate cement, thefiber length of the fiber toughening agent is less than 12cm, the filling material is calcium carbonate powder and the retarder is a composition of boric acid and D-sodium gluconate. The sulphoaluminate clinker, the active admixture, the water-soluble organic material and other raw materials are adopted, so that the plugging agent has the characteristics of high hour strength development speed, high underwater impact resistance, high acid solubility and good thixotropic property at 10-60 DEG C under a specific ratio, and the plugging purpose is achieved by utilizing the characteristics of theplugging agent.

The invention provides well cementing cement paste suitable for coal bed methane. Compared with the prior art, a multi-size-fraction leaking stoppage material, an active filler and a resin material are added into the cement paste to form a leaking stoppage type cement paste system, in the multi-size-fraction leaking stoppage material, the first-stage particle leaking stoppage material serves as asupporting material, and the bridging effect can be achieved to support cracks; gaps are filled with a second-stage particle leaking stoppage material, cement particles and the like to form a leakingstoppage frame, and a hydrophilic fiber leaking stoppage material can form a fiber grid structure in a crack, so that the stability of a cement paste leaking stoppage structure is improved; a resin cementing material is used for further enhancing the mutual cementing among the crack surface, the leaking stoppage material and the cement; therefore, the compactness of the leaking stoppage structureis improved through multistage filling of the bridges, the elasticity, the nano materials and the cement particles, and meanwhile, the addition amounts of the modified multi-size-fraction leaking stoppage material, the active filler and the resin material are adjusted, so that the combined action of the modified multi-size-fraction leaking stoppage material, the active filler and the resin material has a remarkable synergistic effect on the leaking stoppage performance of the cement paste.

The invention relates to a low temperature magnesium oxysulfide thermosetting resin cementitious system and a preparation method thereof, and relates to the field of oil-gas well cementing. The low temperature magnesium oxysulfide thermosetting resin cementitious system has good slurry rheological property and is prone to well cementing construction. By use of a thermosetting resin cementitious material, the elasticity modulus of a consolidator can be effectively reduced, the elasticity of the consolidator is increased, and the impact resistance is improved. The density, rheology, curing time,consolidator strength and other properties of the thermosetting resin system can be further improved or controlled by cooperative use with a magnesium oxysulfide skeleton material. With use of good cementing properties of thermosetting resin, magnesium oxysulfide and metals and the expansion characteristics of magnesium oxide, the cementing strength of a first interface and a second interface canbe improved. While the basic requirements of well cementing engineering are met, the problems of vulnerability and poor cementing of oil well cement can also be solved, and the related shortcomings of oil well cement are overcome. The low temperature magnesium oxysulfide thermosetting resin cementitious system provides a new choice for the field and has broad application prospects.

The invention discloses a preparation method of a retarder used for oil gas well cementing operation, the retarder and an application. The preparation method comprises the following steps: (1) adding2-acrylamido-2-sodium methallyl sulfonate into deionized water and stirring to dissolve, wherein the use amount of the deionized water is 1-3 times of 2-acrylamido-2-sodium methallyl sulfonate; addingan NaOH solution to regulate the pH value of the system to 9-12; (2) adding itaconic acid to the solution obtained in the step (1), heating in thermostatic waterbath till reaching 40-60 DEG C, and keeping for 10-30min, wherein the mass ratio of 2-acrylamido-2-sodium methallyl sulfonate to itaconic acid is (73-75):(25-27); (3) slowly dripping an initiator solution to the solution obtained in step(2); slowly heating to 50-90 DEG C while dripping, and continuing reaction for 2-5h after dripping is completed, so as to obtain a liquid product; and (4) participating by alcohol, drying and smashingthe liquid product obtained in step (3) so as to obtain a product which is white powder. The retarder is small in adding amount, high in application temperature and large in temperature resistant scope span.