The invention discloses an optical ultrasonic imaging device for diagnosing breast cancer, which comprises a bowl-shaped flexible ultrasonic probe, a laser probe, a pulsed laser emitter, an ultrasonicreceiver, a data processing unit and an image display. The device comprises a bowl-shaped flexible ultrasonic probe, a laser probe, a pulsed laser emitter, an ultrasonic receiver, a data processing unit and an image display. The ultrasonic transducer adopts bowl-shaped shell and flexible structure, adopts multi-array array composite wafer structure, utilizes multi-array array composite wafer, andcombines the principle of phased array technology to obtain the signal sources with different initial phases. An ultrasonic transducer is connected to an ultrasonic receiver. A laser probe connectedwith a pulse laser emitter emits a laser beam with a certain frequency to that inside of the tissue, molecules or substances that absorb light at a particular wavelength are called chromophores. The light energy absorbed by the chromophore is converted into heat energy by molecular vibration and thermoelastic expansion to generate ultrasonic wave, which is detected by an ultrasonic sensor in the device, and the waveform signal is synthesized into an image through an ultrasonic receiver and a data processing unit and displayed on an image display.