The invention discloses a measuring method and a measuring device of non-contact electrostatic spraying charge-to-mass ratios, and the measuring method and the measuring device are particularly suitable for calculation of charge-to-mass ratios of charged fogdrops in induction charging and corona charging. The measuring device comprises a laser transmitter (1), an electrostatic sprayer (4), a polarizer (2), a reflector (3), a reflector (3'), a magneto-optical element (6), an analyzer (7), a composite polarized light prism (8), an optical-electrical converter (9), a differential amplifier (10), wires (11) and an oscilloscope (12), wherein the light emitted by the generating laser (1) is a sheet light source. The diameter of the magneto-optical element is D, the distance between the electrostatic sprayer (4) and the magneto-optical element (6) is H, the mist spraying angle of the electrostatic sprayer is theta, and D, H and theta meet the relation that D=2H*tan(theta/2). Current values of all fogdrops on a charged fogdrop group section can be calculated without contact by the utilization of the Faraday magneto-optical effect and the Ampere circuital theorem through the measuring device, then the current values are divided by mass flow rates of a charged foglet group, and the charge-to-mass ratios can be calculated.