The invention belongs to medicament adding technical field, and concretely relates to an intelligent on-line medicament adding system. The system comprises a medicament storage device, a medicament adding pipeline and a control system. The system is characterized in that the medicament adding pipeline includes a medicament conveying pipeline, and the medicament conveying pipeline is provided with a metering pump for adjusting the medicament conveying amount, a PH meter for monitoring PH values and a plurality of valves for controlling the pipeline to be on and off; and the control system includes a PLC core controller, a PID digital-analog controller, a GPRS module, a switch and a DCS controller. On-line acquired analog quantities such as a PH value, a liquid level, flow and temperature are taken as feedback values, a PID mathematic model is established, a fuzzy adaptive control algorithm is optimized, a diagnosis system is established, the medicament adding amount is calculated, then control data is input to the metering pump, and thus the adding amount of medicaments is controlled accurately.