The present invention belongs to the field of perovskites and organic solar cells, and discloses an
acridine-based self-assembled hole-selective material having a structure of formula I: #imgabs0#X and Y are each independently selected from
hydrogen,
alkyl, amino, nitro, alkoxy, and
halogen; L is selected from (C2-C18)
alkyl, phenyl, naphthyl, anthracenyl, thienyl, benzothienyl, dithienothiophene, dithienothiopyrrole, carbazolyl, and fluorenyl; and A is selected from one of the following groups: #imgabs1# The self-assembled hole-selective material of the present invention has the advantages of
high energy level matching, suitable steric hindrance effect, and suitable connecting group length that is conducive to regulating film morphology. It can simultaneously passivate surface defects of a
nickel oxide hole transport layer, induce
perovskite crystal growth, and reduce
energy loss caused by interfacial charge recombination. The self-assembled hole-selective material is applied to an inverted
perovskite solar cell device to obtain a
solar cell with higher photovoltaic performance and high efficiency and stability.