The invention relates to a special amino modified perfluorosulfonic membrane for a fuel cell, and a preparation method, belongs to the technical field of a fuel cell diaphragm and aims to solve the technical problems. The preparation method comprises the steps of performing sulfonation of tetrafluoroethylene, fluorination of 3-amino propylene, a condensation reaction, a condensation polymerizationand acidizing and the like; by virtue of combination of N atoms and dual-short sulfonic acid group branch chains, grafted polymerization on the main chain is realized, so that the sulfonic acid groupcontent and structural symmetry are improved; therefore, the membrane material structure in the swelling process is more stable, and ion clusters can be formed in the membrane material more easily, thereby improving proton adsorption and mobility capabilities; the method is simple in process and high in feasibility; and the prepared amino modified perfluorosulfonic membrane is high in structuralsymmetry, high in regularity, easy to crystallize, relatively high in membrane material mechanical strength, high in proton conductivity and suitable for a high-temperature and low-moisture environment.