This application relates to a low-temperature charging method for lithium-ion batteries. First, a three-electrode battery with a reference electrode is provided; secondly, according to the initial state parameters of the three-electrode battery, the initial pulse current parameters are set, and the initial pulse current parameters are used for the three electrodes. The electrode battery starts to perform pulse charging, and the state parameters include at least one of the battery SOC state, battery temperature and battery SOH state, and the pulse current parameters include pulse waveform, pulse period, positive pulse amplitude, negative pulse amplitude, and positive pulse duration , Negative pulse duration; Finally, during the charging process, the negative electrode potential and battery voltage of the three-electrode battery are monitored in real time, and the pulse current parameters are adjusted according to the negative electrode potential and battery voltage. In the above method, during the charging process, by adjusting the pulse current parameters through the negative electrode potential and the battery voltage, the battery can exert the maximum charging capacity within a safe range without lithium-analysis side reactions, and realize safe and fast charging of the battery.