The invention discloses a shell making process of a silica sol shell with high deshelling property. The shell making process comprises the following steps: S1, uniformly mixing powder with silica solwith stirring, and adding a wetting agent and a defoamer to form a first mixture; S2, immersing a wax mold into the first mixture, taking the wax mold out, scattering sand into the wax mold, and drying to obtain a first-layer mold shell; S3, repeating the step S2 until second to sixth layers of mold shells are obtained; S4, drying the wax mold including the first to sixth layers of mold shells tocomplete sealing; S5, calcining the wax mold including the first to sixth layers of mold shells to obtain a mold shell casting. According to the shell making process of the silica sol shell with highdeshelling property disclosed by the invention, fully-calcined aluminosilicate refractory sand powder, free iron and hard kaolinite with low diaspore content is taken as a main material of the silicasol shell, and is combined skillfully with quartz sand, so that the high-temperature strength of the mold shell is ensured, and the retained strength after mold shell pouring can be lowered greatly.