The invention discloses a quick determining method for content of peroxy-monosulfate in solution, and relates to a determining method of peroxy-monosulfate, which aims at solving the problems of complicated operation, long determining time, toxicity of test reagent, large error of determining result, high determining cost, and use of expensive instrument and equipment in determining, and the like in the existing determining method. The quick determining method has the advantages that N,N-diethyl-p-phenylenediamine is used as an indication agent to quickly determine the content of the peroxy-monosulfate in a to-be-determined sample; the operation is simple and convenient, the stability is good, the green and environment-friendly effects are realized, the economic and practical effects are realized, and the content of peroxy-monosulfate in the sample can be quickly determined in laboratories and field by only using an ultraviolet and visible spectrophotometer; the response time is short, the sensitivity is high, and the minimum determining content of peroxy-monosulfate can reach 0.05mumol L<-1>; the method can be widely applied to the quick, environment-friendly and effective detection of the content of peroxy-monosulfate in the chlorinating, bleaching or disinfection samples in environment protection, dye printing and medical care industries.