The invention relates to an organic thermal control coating with low solar absorptivity and a preparation method. The coating comprises a bottom coating, a middle coating and a surface coating. The bottom coating, the middle coating and the surface coating all take space-stable organic silicon resin as an adhesive; zinc orthotitanate is selected as a coating filler in the bottom coating, the zinc orthotitanate is spherical, the particle size is 1-3 microns, the purity is greater than or equal to 99.99%, and the pigment-agent ratio is 3-5; the middle coating adopts a rare earth oxide as a coating filler, the rare earth oxide is one or more of lanthanum oxide, europium oxide, yttrium oxide, samarium oxide and gadolinium oxide, the rare earth oxide is spherical, the particle size is 3-5 microns, the purity is greater than or equal to 99.99%, and the pigment-agent ratio is 3-5; the surface coating selects zinc oxide as a coating filler, the zinc oxide is spherical, the particle size of the filler is 50-200nm, the purity is greater than or equal to 99.99%, and the pigment ratio is 1.5-3.5. The scattering capability of different spectral energy of sunlight and the vacuum ultraviolet radiation stability are greatly improved, so that the design requirements of high precision and long service life of a modern novel spacecraft can be met.