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33results about How to "Deterioration of physical property" patented technology

Water absorbing agent, water absorbing article and method for production of water absorbing agent

An object of the present invention is to provide a water absorbing agent having a low amount of residual monomer, small variance of the amount of residual monomer among ranges of particle size distribution and favorable absorption properties, and being sanitary; an absorbing article; and a method for the production of a water absorbing agent. The water absorbing agent of the present invention has the amount of residual monomer of not higher than 500 ppm, and a residual monomer index of not greater than 0.30. The method for the production includes a first step of obtaining a hydrogel polymer by polymerizing an aqueous solution of a monomer including an unsaturated carboxylic acid and / or a salt thereof in the presence of a crosslinking agent; a second step of obtaining a water absorbent resin precursor which is in powder form and includes particles having a particle size of 300 to 850 μm and particles having a particle size of smaller than 300 μm as main components by drying said hydrogel polymer followed by pulverization and classification to adjust the particle size distribution, a third step of obtaining a water absorbent resin by heating a mixture of said water absorbent resin precursor and a surface crosslinking agent, which can form an ester bond around the surface of said water absorbent resin precursor, a fourth step of adding by spraying an aqueous solution that includes a sulfur-containing reducing agent to said water absorbent resin, and a fifth step of subjecting the mixture of the water absorbent resin and said aqueous solution to a heat treatment under an airflow of not lower than 40° C. but not higher than 120° C.
Owner:NIPPON SHOKUBAI CO LTD

Thermoplastic elastomeric resin composition and a process for the preparation thereof

The invention provides a process for the preparation of a thermoplastic elastomeric resin composition comprising melt kneading (a) 100 parts by weight of a block copolymer consisting of at least two polymeric blocks (A) composed mainly of a vinyl aromatic compound and at least one polymeric block (B) composed mainly of a conjugated diene compound, and / or a hydrogenated block copolymer obtained by hydrogenating said block copolymer, (b) 40 to 240 parts by weight of a non-aromatic softening agent for rubber, (c) 5 to 300 parts by weight of polyethylene or a copolymer composed mainly of ethylene, and (d) 5 to 60 parts by weight of polypropylene or a copolymer composed mainly of propylene, characterized in that the process comprises the following steps: (I) melt kneading the whole amounts of components (a), (b) and (d) and a part of component (c), and, at the same time or subsequently, melt kneading these with (f) an organic peroxide, and (II) melt kneading the product obtained from step (I) with the remaining part of component (c), and component (c) is one which has been prepared using a single site catalyst. The obtained composition is soft and excellent in heat deformation resistance and mechanical strength, moldability and processability. The present invention also provide a thermoplastic elastomeric resin composition comprising the above components (a), (c) and (d) in an amount of 100 parts by weight, 5 to 150 parts by weight and 5 to 80 parts by weight, respectively. The composition is soft and excellent in heat deformation resistance and mechanical strength, moldability and processability and shows good results in the extraction tests.
Owner:RIKEN TECHNOS CORP

Thermoplastic elastomeric resin composition and a process for the preparation thereof

The invention provides a process for the preparation of a thermoplastic elastomeric resin composition comprising melt kneading(a) 100 parts by weight of a block copolymer consisting of at least two polymeric blocks (A) composed mainly of a vinyl aromatic compound and at least one polymeric block (B) composed mainly of a conjugated diene compound, and/or a hydrogenated block copolymer obtained by hydrogenating said block copolymer,(b) 40 to 240 parts by weight of a non-aromatic softening agent for rubber,(c) 5 to 300 parts by weight of polyethylene or a copolymer composed mainly of ethylene, and(d) 5 to 60 parts by weight of polypropylene or a copolymer composed mainly of propylene,characterized in that the process comprises the following steps:(I) melt kneading the whole amounts of components (a), (b) and (d) and a part of component (c), and, at the same time or subsequently, melt kneading these with (f) an organic peroxide, and(II) melt kneading the product obtained from step (I) with the remaining part of component (c),and component (c) is one which has been prepared using a single site catalyst.The obtained composition is soft and excellent in heat deformation resistance and mechanical strength, moldability and processability. The present invention also provide a thermoplastic elastomeric resin composition comprising the above components (a), (c) and (d) in an amount of 100 parts by weight, 5 to 150 parts by weight and 5 to 80 parts by weight, respectively. The composition is soft and excellent in heat deformation resistance and mechanical strength, moldability and processability and shows good results in the extraction tests.
Owner:RIKEN TECHNOS CORP
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