A flip-chip LED chip and a manufacturing method thereof are provided, A buff layer and a light emitting structure are sequentially formed on that substrate, wherein the light emitting structure includes a first semiconductor layer, an active layer, a second semiconductor layer, metal reflective electrode layer, metal barrier layer, first reflective passivation layer, a first electrode and a secondelectrode, forming a second reflective passivation layer on the surface of the light emitting structure, etching the second reflective passivation layer, forming a first bare region on the surface ofthe first electrode, forming a second bare region on the surface of the second electrode, forming a first pad on the first bare region, and forming a second pad on the second bare region. The light emitted from the active layer passes through the metal reflective electrode layer, the first reflective passivation layer and the second reflective passivation layer, part of which is refracted from the side wall of the flip chip and part of which is reflected back to the side of the substrate, thereby greatly improving the light emitting efficiency of the active layer without adding additional complex processes, thereby increasing the brightness of the chip.