The invention relates to the technical field of high-purity
boron-doped
silicon carbide powder and a
solid-
phase synthesis method thereof, and particularly discloses high-purity
boron-doped
silicon carbide powder and a
solid-
phase synthesis method thereof. The invention aims to solve the problems that the
boron doping concentration is uncontrollable, the component distribution is uneven, the
impurity content is high and the
powder particle size does not meet the
crystal growth requirement of a physical vapor transport method in the existing preparation of the p-type
silicon carbide single crystal raw material. The method comprises the following steps: mixing high-purity carbon powder, silicon powder and a boron source in proportion; the preparation method comprises the following steps: firstly, generating
silicon carbide crystal nucleuses at the constant temperature of 1350-1500 DEG C under the protection of
inert gas filled after vacuum, and then promoting
grain growth and uniform
doping of boron at the constant temperature of 2100-2300 DEG C and 13.3-66.7 kPa; and cooling, crushing, screening, cleaning and
drying to obtain target powder. By the adoption of the technical scheme, precise regulation and control of the
boron doping concentration
ranging from 0.01 at% to 5 at%, customized growth with the particle size
ranging from 0.1 mm to 3 mm and high cleanliness with the purity higher than 99.999% can be achieved, the powder fluidity is good, and the requirements for growth of high-performance p-type
silicon carbide single crystals and application of high-thermal-
conductivity ceramic substrates are completely met.