The invention discloses a polyurethane paint used on windward sides of wind power blade machines, and a preparation method thereof. The polyurethane paint comprises modified phenolic resin reinforced polyurethane, urea-formaldehyde resin, ethylene-vinyl acetate copolymer, an anti-settling agent, rutile titanium dioxide, flake graphite powder, methyl methacrylate, coumarone, zinc oxide, kaolin, diethylene glycol, an aromatic hydrocarbon oil, a stabilizing agent, silicon dioxide, an antifoaming agent, a dispersant, a base material wetting agent, and a bactericide. The polyurethane paint is long in service life, and high in using safety, is capable of reducing blade production cost and maintenance cost in operation process. It is confirmed by a plurality of performance tests that the polyurethane paint is excellent in adhesive force, wear resistance, weatherability, salt spray resistance, damp heat resistance, and flexibility, can be used on wind driven generator blades, and is capable of protecting operation of wind driven generator blades for a long term.