The invention provides a method for determination of inorganic element in fuel gas, comprising the following steps: sample collection: the fuel gas is divided into two parts so as to flow through cation absorption liquid and anion absorption liquid respectively after the fuel gas flows through a filter membrance; sample handling: the filter membrance is equally divided into two parts, one part of the filter membrance is dispelled by acid liquor, then the cation absorption liquid is added, and through metered volume and filtering, filtrate for cation analysis is obtained, and the other part of the filter membrance is extracted with water, then the anion absorption liquid is added into the extract liquor, and through metered volume and filtering, filtrate for anion analysis is obtained; sample analysis: above filtrates are respectively subsjected to capillary electrophoresis test, and then data is treated. According to the method and the device provided by the invention, the defects of low efficiency, long consuming time, higher analytical cost and difficult in popularizing in traditional method are overcame. The aim to quick test multiple inorganic elements is realized, the operation cost is lower, the operation is simple, and the method is convenient to popularize.