The invention discloses a preparation method for chlorinated
polypropylene resin. The preparation method comprises the following steps of: (1) fully swelling
polypropylene in a
solvent, adding a lattice
destructive agent, uniformly dispersing the lattice
destructive agent in the
solvent, adding an initiator to initiate reaction, adding the mixture of an emulsifier and water, fully mixing and dispersing to form
emulsion, and filtering, washing the
emulsion with water and
drying the
emulsion to obtain
polypropylene powder; and (2) dissolving the polypropylene
powder into a mixed
solvent formed by
trichloroethane and water, fully mixing and dispersing, heating, adding the initiator, introducing a
chlorine gas to react after mixing and dispersing the initiator uniformly, removing the
residual chlorine gas from the liquid after the chlorination degree reaches a set value, and obtaining the chlorinated polypropylene resin by performing two-phase separation, washing with water, neutralizing,
drying and crushing. The chlorinated polypropylene produced by the invention is chlorinated uniformly, and can be fully dissolved in the solvents such as dimethylbenzene, methylbenzene,
ketone solvents and environment-friendly
butyl acetate solvents. In addition, through the preparation method disclosed by the invention, the product with controllable chlorination degree can be prepared.