This invention discloses a method for preparing ultra-
low oxygen metallic
vanadium. First,
vanadium oxide and aluminum
powder are used as raw materials, with aluminum-
calcium alloy particles added as a composite
reducing agent and synergistic deoxidizer to prepare a low-
oxygen vanadium-aluminum
alloy.
Electron beam melting is then used to deeply remove
metallic impurities such as aluminum,
calcium, and iron, resulting in a dense, high-purity, low-
oxygen vanadium plate. Next, the vanadium plate undergoes low-temperature vacuum
diffusion deoxidation with
calcium powder embedding to deeply remove dissolved
oxygen in the
crystal lattice, ultimately obtaining ultra-
low oxygen high-purity metallic vanadium. This invention overcomes the deoxidation limit of V-O
solid solutions through a three-stage
coupling of aluminum-calcium synergistic reduction,
electron beam refining, and calcium embedding low-temperature deoxidation. The process is short, highly synergistic, and suitable for industrial production. The resulting high-purity metallic vanadium has an
oxygen content ≤30ppm and a purity ≥99.9%, making it suitable for high-end fields such as
radio frequency superconducting cavities, magnetron
sputtering targets,
nuclear industry structural materials, and superconducting electronic devices.