The invention discloses an RFID (radio frequency identification) passive sensing device for measuring the temperature of the cable head conductor of a ring main cabinet. The device comprises an RFID passive sensor, an RFID temperature reader antenna and an RFID temperature reader; the RFID passive sensor comprises a passive temperature measuring mechanism and an electromagnetic shielding mechanism, wherein the passive temperature measuring mechanism includes a first housing, an RFID tag, a temperature sensor, and a temperature measuring contact; the RFID temperature reader includes a second housing, an integrated sealing cover, a wireless transmitting/receiving module, an external communication module, a controller, a storage battery and a display screen; and the RFID temperature reader antenna and the controller are connected with each other. The RFID (radio frequency identification) passive sensing device for measuring the temperature of the cable head conductor of the ring main cabinet of the invention has the advantages of reasonable structure, simple structure, convenient use, strong anti-interference capacity, small size, high stability, convenient installation, long readingdistance, high safety, high reliability and the like. With the device of the invention adopted, the problem of potential safety hazards during the measurement of the temperature of the cable head conductors of ring network cabinets in the prior art can be solved.