The application discloses a covalent
triazine framework temperature-responsive
nanofiltration membrane in the technical field of
nanofiltration membranes, a preparation method thereof and application thereof in
lithium selective separation, and relates to a covalent
triazine framework temperature-responsive
nanofiltration membrane, which comprises a support membrane and a separation layer arranged on the support membrane, wherein the separation layer comprises covalent
triazine skeleton nanomaterial, polyethyleneimine (PEI) and a temperature-
responsive polymer; the covalent triazine skeleton nanomaterial is synthesized into CTF-0 and CTF-NH
nanomaterials, and is poured onto the surface of a PEI modified support membrane in sequence, and is constructed on the surface of the PEI modified support membrane through
ultraviolet irradiation; the temperature-
responsive polymer is grafted to the surface and / or the inner wall of pores of the separation layer, and the temperature-
responsive polymer can reversibly change the segment conformation under temperature stimulation, so as to reversibly change the pore size and / or the hydrophilic-hydrophobic property of the separation layer; and the covalent triazine framework temperature-responsive nanofiltration membrane prepared by the application can simultaneously improve the flux and selectivity of the membrane and enhance the anti-
pollution ability of the membrane, and provides a feasible path for the development of a next-generation high-performance self-adapting separation membrane material.