The present application provides a kind of based on off-axis integrated cavity output spectrum (OA-ICOS) transmission spectrum
signal atmospheric
methane concentration retrieval method.For the integral
absorbance concentration retrieval method transmission spectrum
signal is susceptible to
baseline drift and
noise interference and other factors, lead to integral area
calculation error is larger, concentration retrieval precision low problem, the present application proposes a kind of based on transmission spectrum
methane concentration retrieval method, by modeling and optimization to transmission spectrum
signal, realize the high-precision retrieval of
methane concentration.First, the integral absorption area of transmission spectrum is mathematically deduced, and the equivalent expression of integral area is obtained;On this basis, combined with initialization baseline and fitting integral area, construct transmission
light intensity model.Subsequently, the Levenberg-Marquardt (L-M) nonlinear
least squares optimization
algorithm is used to iteratively optimize the parameters in the transmission
light intensity model, to obtain the optimal solution of the fitting integral area, and further establish a polynomial prediction model between methane concentration and integral absorption area, realize the inversion calculation of methane concentration.Experimental results show that the method provided by the present application can effectively reduce the influence of
baseline drift on integral area calculation, improve the accuracy of methane concentration retrieval, and is suitable for deep-sea gas exploration, park environmental
gas monitoring and other application scenarios.