Belonging to the field of dispersants, the invention provides a method for preparation of high mud resistant polycarboxylic acid dispersant by unsaturated halogenated
hydrocarbon copolymerization and
grafting with a cationic
side chain. The method consists of: employing an unsaturated
carboxylic acid monomer, an unsaturated halogenated
hydrocarbon monomer, an unsaturated cationic
quaternary ammonium salt
monomer, a
polyethylene glycol compound and the like as the raw materials, firstly conducting main chain copolymerization, then polymerizing the cationic
side chain, performing functionalization, and finally carrying out etherification
grafting so as to synthesize the excellent performance high mud resistant polycarboxylic acid dispersant material with unsaturated halogenated
hydrocarbon copolymerized and grafted with cationic
side chain, i.e. taking unsaturated
carboxylic acid and unsaturated halogenated hydrocarbon as the reactants, conducting free
radical polymerization to obtain a
carboxylic acid-halogenated hydrocarbon
copolymer main chain, using high valence
cerium salt-
alcohol to initiate
polymerization of an unsaturated cationic
quaternary ammonium salt monomer so as to obtain a hydroxyl terminated cationic side chain, then modifying the hydroxyl terminated cationic side chain and the
polyethylene glycol compound to obtain a functionalized side chain, and carrying out etherification
grafting of the functionalized side chain on the carboxylic acid-halogenated hydrocarbon
copolymer main chain. The method provided by the invention realizes high water reduction,
slump loss resistance, high clay resistance and other multiple effects.