The invention discloses a method for preparing biodegradable ocean antifouling
polyurethane hybrid materials and a product thereof. The method for preparing the biodegradable ocean antifouling
polyurethane hybrid materials and the product thereof adopt
stannous octoate as a catalyst, adopts double hydroxyl functional
grapheme which is prepared by adopting reduction
grapheme to react with 2, 2-hydroxy
benzaldehyde and N-
glycine as an initiator, and the initiator triggers L-
lactide monomers to prepare
graphene grafted poly lactic acids through
ring opening polymerization. 1, 4-
butanediol and 4, 4-diphenyl
methane diisocyanate prepare
polyurethane prepolymers containing
Isocyanate functional groups on the
tail ends through condensation
polymerization. The biodegradable ocean antifouling polyurethane
hybrid materials are prepared by utilizing a
chemical reaction between
graphene grafted hydroxyl-terminated poly lactic acids and polyurethane prepolymers. The method for preparing biodegradable ocean antifouling polyurethane hybrid materials and the product thereof improve strength of target materials by leading into
grapheme, and the grapheme plays the role of antibacterial function during the
degradation process, and control
crystallinity and hydrophobic property of grafted poly
lactide by adjusting the contents of the grapheme and the L-
lactide monomers, thereby effectively adjusting and controlling degradation of polyurethane. hybrid materials which are prepared through the method for preparing biodegradable ocean antifouling polyurethane hybrid materials has excellent mechanical properties and can adjust degradation rate, degradation products are non-toxic and do not pollute the environment, and can be applied in antifouling
marine coatings and
drug controlled release carriers in a biomedical medical
engineering.