The invention discloses a method for preparing biodegradable ocean antifouling 
polyurethane hybrid materials and a product thereof. The method for preparing the biodegradable ocean antifouling 
polyurethane hybrid materials and the product thereof adopt 
stannous octoate as a catalyst, adopts double hydroxyl functional 
grapheme which is prepared by adopting reduction 
grapheme to react with 2, 2-hydroxy 
benzaldehyde and N-
glycine as an initiator, and the initiator triggers L-
lactide monomers to prepare 
graphene grafted poly lactic acids through 
ring opening polymerization. 1, 4-
butanediol and 4, 4-diphenyl 
methane diisocyanate prepare 
polyurethane prepolymers containing 
Isocyanate functional groups on the 
tail ends through condensation 
polymerization. The biodegradable ocean antifouling polyurethane 
hybrid materials are prepared by utilizing a 
chemical reaction between 
graphene grafted hydroxyl-terminated poly lactic acids and polyurethane prepolymers. The method for preparing biodegradable ocean antifouling polyurethane hybrid materials and the product thereof improve strength of target materials by leading into 
grapheme, and the grapheme plays the role of antibacterial function during the 
degradation process, and control 
crystallinity and hydrophobic property of grafted poly 
lactide by adjusting the contents of the grapheme and the L-
lactide monomers, thereby effectively adjusting and controlling degradation of polyurethane. hybrid materials which are prepared through the method for preparing biodegradable ocean antifouling polyurethane hybrid materials has excellent mechanical properties and can adjust degradation rate, degradation products are non-toxic and do not pollute the environment, and can be applied in antifouling 
marine coatings and 
drug controlled release carriers in a biomedical medical 
engineering.