The invention discloses a poly-heterocyclic ring based 
acrylate monomer modified waterborne hydroxy acrylic dispersion and a preparation method thereof. The dispersion comprises, by weight, 20-50 parts of solvents, 5-10 parts of poly-heterocyclic ring based 
acrylate monomers, 50-70 parts of acrylic 
alkyl ester, 25-30 parts of acrylic functional monomers, 1-3 parts of 
chain transfer agents, 2-4 parts of initiators, 1-3 parts of anion exchange reactive emulsifiers, 2-4 parts of initiators, 100-120 parts of deionized water, 0.1-0.5 part of 
defoaming agents, 0.2-0.6 part of leveling agents and 0.3-0.8 part of 
wetting agents. The glossiness of a film is higher than 97 degrees, the 
hardness of the film reaches up to 2H, the film is strong in 
impact resistance, excellent in flexibility and 
adhesive force, and the dispersion has prominent 
chemical corrosion resistance such as 
acid resistance, alkali resistance and 
water resistance, meets natural zero-VOC (volatile organic compounds) paint standards, is 
environmentally friendly, non-toxic and free from 
pollution and can be used for waterborne wood paint, waterborne industrial paint and waterborne floor paint.